Delignification of Rice Husk by Microwave Assisted Chemical Pretreatment

Authors

  • S. M. Laghari Civil Engineering Department, Universiti Teknologi Petronas, Malaysia
  • M. M. Tunio Department of Energy and Environment Engineering, Quaid-e-Awam University of Engineering, Science and Technology, Nawabshah, Pakistan
  • A. Q. Laghari Department of Chemical Engineering, Mehran University of Engineering & Technology, Pakistan
  • A. J. Laghari Dr. M. A. Kazi Institute of Chemistry, University of Sindh, Jamshoro, Pakistan
  • A. M. Ali Chemical Engineering Department, Mehran University of Engineering & Technology, Pakistan

Abstract

Rice husk has the potential to be used as a source of alternative energy e.g. as biofuel. Its high lignin content, however, poses difficulty to this use. This study investigates the use of microwave assisted acidic and alkaline pretreatment methods to improve the characteristics of rice husk for energy production. The use of microwave assisted 3.5% NaOH provided optimum pretreatment of rice husk; the lignin content was reduced from 17.8 to 10.2%, the cellulose content increased from 38.6 to 59.3% and the C/N ratio was within the optimum range of 25-35. The results showed enhanced potential of biofuel production from rice husk by this pretreatment.

Keywords:

chemical pretreatment, microwave, rice husk, lignocellulose biomass

Downloads

Download data is not yet available.

References

M. Fatih Demirbas, M. Balat, H. Balat, “Biowastes-to-biofuels”, Energy Conversion and Management, Vol. 52, No. 4, pp. 1815-1828, 2011 DOI: https://doi.org/10.1016/j.enconman.2010.10.041

C. Escamilla-Alvarado, E. Ríos-Leal, M. T. Ponce-Noyola, H. M. Poggi-Varaldo, “Gas biofuels from solid substrate hydrogenogenic–methanogenic fermentation of the organic fraction of municipal solid waste”, Process Biochemistry, Vol. 47, No. 11, pp. 1572-1587, 2012 DOI: https://doi.org/10.1016/j.procbio.2011.12.006

UNEP, Converting Waste Agricultural Biomass into a Resource, United Nations Environmental Programme, Osaka/Shiga, Japan, 2009

R. Chandra, H. Takeuchi, T. Hasegawa, “Methane production from lignocellulosic agricultural crop wastes: A review in context to second generation of biofuel production”, Renewable and Sustainable Energy Reviews, Vol. 16, No. 3, pp. 1462-1476, 2012 DOI: https://doi.org/10.1016/j.rser.2011.11.035

K. Starr, G. Villalba, X. Gabarrell, “Upgraded biogas from municipal solid waste for natural gas substitution and CO2 reduction–A case study of Austria, Italy, and Spain”, Waste Management, Vol. 38, pp. 105-116, 2015 DOI: https://doi.org/10.1016/j.wasman.2015.01.001

A. T. W. M. Hendriks, G. Zeeman, “Pretreatments to enhance the digestibility of lignocellulosic biomass”, Bioresource Technology, Vol. 100, No. 1, pp. 10-18, 2009 DOI: https://doi.org/10.1016/j.biortech.2008.05.027

T. -C. Hsu, G. -L. Guo, W. -H. Chen, W. –S. Hwang, “Effect of dilute acid pretreatment of rice straw on structural properties and enzymatic hydrolysis”, Bioresource Technology, Vol. 101, pp. 4907-4913, 2010 DOI: https://doi.org/10.1016/j.biortech.2009.10.009

Y. C. Park, J. S. Kim, “Comparison of various alkaline pretreatment methods of lignocellulosic biomass”, Energy, Vol. 47, pp. 31-35, 2012 DOI: https://doi.org/10.1016/j.energy.2012.08.010

L. S. Monte, V. A. Escócio, A. M. F. de Sousa,C. R. G. Furtado, M. C. A. M. Leite, L. L. Y. Visconte, E. B. A. V. Pacheco, “Study of time reaction on alkaline pretreatment applied to rice husk on biomass component extraction”, Biomass Conversion and Biorefinery, Vol. 8, No. 189, 2018 DOI: https://doi.org/10.1007/s13399-017-0271-9

C. J. Chang, V. K. Tyagi, S. –L. Lo, “Effects of microwave and alkali induced pretreatment on sludge solubilization and subsequent aerobic digestion”, Bioresource Technology, Vol. 102, pp. 7633-7640, 2011 DOI: https://doi.org/10.1016/j.biortech.2011.05.031

S. Zhu, Y. Wu, Z. Yu, J. Liao, Y. Zhang, “Pretreatment by microwave/alkali of rice straw and its enzymic hydrolysis”, Process Biochemistry, Vol. 40, pp. 3082-3086, 2005 DOI: https://doi.org/10.1016/j.procbio.2005.03.016

W. H. Chen, Y. –J. Tu, H. –K. Sheen, “Disruption of sugarcane bagasse lignocellulosic structure by means of dilute sulfuric acid pretreatment with microwave-assisted heating”, Applied Energy, Vol. 88, pp. 2726-2734, 2011 DOI: https://doi.org/10.1016/j.apenergy.2011.02.027

Y. Chen, Y. Zhu, Z. Wang, Y. Li, L. Wang, L. Ding, X. Gao, Y. Ma, Y. Guo, “Application studies of activated carbon derived from rice husks produced by chemical-thermal process--a review”, Advances in Colloid and Interface Science, Vol. 163, No. 1, pp. 39-52, 2011 DOI: https://doi.org/10.1016/j.cis.2011.01.006

A. Abbas, S. Ansumali, “Global potential of rice husk as a renewable feedstock for ethanol biofuel production”, BioEnergy Research, Vol. 3, pp. 328-334, 2010 DOI: https://doi.org/10.1007/s12155-010-9088-0

T. N. Ang, G. C. Ngoh, A. S. M. Chua, “Comparative study of various pretreatment reagents on rice husk and structural changes assessment of the optimized pretreated rice husk”, Bioresource Technology, Vol. 135, pp. 116-119, 2013 DOI: https://doi.org/10.1016/j.biortech.2012.09.045

S. Banerjee, R. Sen, R. Pandey, T. Chakrabarti, D. Satpute, B. S. Giri, S. Mudliar, “Evaluation of wet air oxidation as a pretreatment strategy for bioethanol production from rice husk and process optimization”, Biomass Bioenergy, Vol. 33, pp. 1680-1686, 2009 DOI: https://doi.org/10.1016/j.biombioe.2009.09.001

W. Shi, J. Jia, Y. Gao, Y. Zhao, “Influence of ultrasonic pretreatment on the yield of bio-oil prepared by thermo-chemical conversion of rice husk in hot-compressed water”, Bioresource Technology, Vol. 146, pp. 355-362, 2013 DOI: https://doi.org/10.1016/j.biortech.2013.07.094

M. Nikzad, K. Movagharnejad, G. D. Najafpour, F. Talebnia, “Comparative studies on effect of pretreatment of rice husk for enzymatic digestibility and bioethanol production”, International Journal of Engineering, Vol. 26, pp. 455-464, 2013 DOI: https://doi.org/10.5829/idosi.ije.2013.26.05b.01

R. R. Sluiter, C. Scarlata, J. Sluiter, D. Templeton, Determination of Extractives in Biomass. National Renewable Energy Laboratory, 2005

M. P. da Rosa, P. H. Beck, D. G. Müller, J. B. Moreira, J. S. da Silva, A. M. M. Durigon, “Extraction of organosolv lignin from rice husk under reflux conditions”, Biological and Chemical Research, pp. 87-98, 2017.

Faber, FABER Microwave Oven Instruction Manual, Model: FMO 7020

A. Sluiter, B. Hames, R. Ruiz, C. Scarlata, J. Sluiter, D. Templeton, D. Crocker, Determination of structural carbohydrates and lignin in biomass, National Renewable Energy Laboratory, U. S. Department of Energy, 2012

A. Sluiter, B. Hames, D. Hyman, C. Payne, R. Ruiz, C. Scarlata, J. Sluiter, D. Templeton, J. Wolfe, Determination of total solids in biomass and total dissolved solids in liquid process samples, National Renewable Energy Laboratory, U. S. Department of Energy, 2008

A. Sluiter, B. Hames, R. Ruiz, C. Scarlata, J. Sluiter, D. Templeton, Determination of ash in biomass laboratory analytical procedure (LAP), National Renewable Energy Laboratory, U. S. Department of Energy, 2008

W. Mussoline, G. Esposito, A. Giordano, P. Lens, “The anaerobic digestion of rice straw: a review”, Critical Reviews in Environmental Science and Technology, Vol. 43, No. 9, pp. 895-915, 2013 DOI: https://doi.org/10.1080/10643389.2011.627018

P. C. Badger, “Ethanol from cellulose: a general review” in: Trends in New Crops and New Uses, ASHS Press, Alexandria, 2002

A. W. Khan, T. M. Trottier, G. B. Patel, S. M. Martin, “Nutrient requirement for the degradation of cellulose to methane by a mixed population of anaerobes”, Journal of General Microbiology, Vol. 112, pp. 365-372, 1979 DOI: https://doi.org/10.1099/00221287-112-2-365

Downloads

How to Cite

[1]
Laghari, S.M., Tunio, M.M., Laghari, A.Q., Laghari, A.J. and Ali, A.M. 2018. Delignification of Rice Husk by Microwave Assisted Chemical Pretreatment. Engineering, Technology & Applied Science Research. 8, 3 (Jun. 2018), 3084–3087. DOI:https://doi.org/10.48084/etasr.2143.

Metrics

Abstract Views: 991
PDF Downloads: 519

Metrics Information

Most read articles by the same author(s)