Processing of Technogenic Gold-Bearing Raw Materials Using Preliminary Energy-Efficient Microwave Treatment
Received: 18 October 2025 | Revised: 12 November 2025 | Accepted: 19 November 2025 | Online: 11 December 2025
Corresponding author: Zhanserik Shoshay
Abstract
This paper examines energy-efficient and environmentally friendly methods of processing technogenic gold-bearing raw materials. The main focus is on studying the kinetics of the thiourea leaching process after the preliminary oxidative roasting of gold-bearing materials obtained from technogenic waste from a gold extraction plant. This study compares traditional roasting in an electric furnace with roasting in a chemical reactor with microwave treatment. Preliminary oxidative microwave roasting was found to achieve a higher thiourea leaching reaction rate due to better exposure of refractory gold. Compared to traditional oxidative heating, roasting in a microwave-assisted chemical reactor reduces processing time and energy consumption while improving the degree of preparation of the raw materials for subsequent gold leaching and increasing gold recovery by 17.8%. This reduction in activation energy is due to preliminary oxidative roasting with microwave treatment (P 1.1 kW, frequency 2.45 GHz, 700 °C for 10 min), which results in an energy reduction of 14.716 kJ/mol versus 22.630 kJ/mol for traditional oxidative roasting in an electric furnace (750 °C for 60 min).
Keywords:
gold, microwave, kinetics, thiourea, leachingDownloads
References
M. Marinin, O. Marinina, and R. Wolniak, "Assessing of Losses and Dilution Impact on the Cost Chain: Case Study of Gold Ore Deposits," Sustainability, vol. 13, no. 7, Jan. 2021, Art. no. 3830. DOI: https://doi.org/10.3390/su13073830
D. Turysbekov, N. Tussupbayev, S. Narbekova, and Z. Kaldybayeva, "Effect of Water-Air Microemulsion of Flotation Agent Solution on Flotation of Polymetallic Sulfide Ores," Minerals, vol. 12, no. 12, Dec. 2022, Art. no. 1612. DOI: https://doi.org/10.3390/min12121612
L. Dong, S. Deng, and F. Wang, "Some developments and new insights for environmental sustainability and disaster control of tailings dam," Journal of Cleaner Production, vol. 269, Oct. 2020, Art. no. 122270. DOI: https://doi.org/10.1016/j.jclepro.2020.122270
"Maps.| U.S. Geological Survey," Nov. 25, 2025. https://www.usgs.gov/products/maps.
"World Gold Council | The Authority on Gold," World Gold Council, Dec. 05, 2025. https://www.gold.org.
B. Surimbayev et al., "Gravity Concentration of Gold-Bearing Ores and Processing of Concentrates: A Review," Mineral Processing and Extractive Metallurgy Review, vol. 46, no. 7, pp. 726–750, Oct. 2025. DOI: https://doi.org/10.1080/08827508.2024.2395824
M. K. Guner, G. Bulut, A. Hassanzadeh, S. Lode, and K. Aasly, "Automated Mineralogy and Diagnostic Leaching Studies on Bulk Sulfide Flotation Concentrate of a Refractory Gold Ore," Minerals, vol. 13, no. 10, Oct. 2023, Art. no. 1243. DOI: https://doi.org/10.3390/min13101243
"LBMA Precious Metal Prices," LBMA. https://www.lbma.org.uk/prices-and-data/precious-metal-prices.
M. H. Karimi Darvanjooghi, S. Magdouli, and S. K. Brar, "Recent challenges in biological cyanidation and oxidation of sulfide-based refractory gold ore," World Journal of Microbiology and Biotechnology, vol. 40, no. 2, Jan. 2024, Art. no. 67. DOI: https://doi.org/10.1007/s11274-024-03887-2
P. Mutimutema, G. Akdogan, and M. Tadie, "Evaluation of pre-treatment methods for gold recovery from refractory calcine tailings," Journal of the Southern African Institute of Mining and Metallurgy, vol. 122, no. 10, pp. 561–570, Oct. 2022. DOI: https://doi.org/10.17159/2411-9717/2070/2022
S. J. Chingwaru, M. Tadie, and B. Von der Heyden, "Characterization of Gold in Complex Historical Refractory Tailings for Enhanced Process Optimization," Mineral Processing and Extractive Metallurgy Review, vol. 46, no. 2, pp. 193–209, Feb. 2025. DOI: https://doi.org/10.1080/08827508.2023.2298728
V. I. Bragin, V. A. Makarov, N. F. Usmanova, P. N. Samorodskii, B. M. Lobastov, and A. I. Vashlaev, "Mineralogical Examination of Gold Processing Plant Tailings," Journal of Mining Science, vol. 55, no. 1, pp. 149–156, Jan. 2019. DOI: https://doi.org/10.1134/S1062739119015407
L. V. Semushkina, N. K. Tussupbayev, D. K. Turysbekov, S. M. Narbekova, and A. A. Mukhanova, "Recycling technology for gold-containing tailings with the use of a composite reagent microemulsion," Metalurgija, vol. 61, no. 1, pp. 277–280, Jan. 2022.
F. Zhu et al., "Gold Extraction from Cyanidation Tailing Using Microwave Chlorination Roasting Method," Metals, vol. 8, no. 12, Dec. 2018, Art. no. 1025. DOI: https://doi.org/10.3390/met8121025
S. M.g, E. Y. Jabborov, M. Z. Abdikarimov, A. A. Normurodov, and A. S. Usmonov, "Study Of Gravity Separation Enrichment And Material Composition Of Stockpiled Technogenic Waste From The Marjanbulak Gold Extraction Plant," American Journal Of Applied Science And Technology, vol. 5, no. 03, pp. 25–30, Mar. 2025. DOI: https://doi.org/10.37547/ajast/Volume05Issue03-05
Sudibyo et al., "Taguchi optimization: Case study of gold recovery from amalgamation tailing by using froth flotation method," Proceedings of the 1st International Process Metallurgy Conference (IPMC 2016), West Java, Indonesia, 2017, Art. no. 050003. DOI: https://doi.org/10.1063/1.4974434
Y. Ait-khouia, M. Benzaazoua, A. Elghali, A. Chopard, and I. Demers, "Feasibility of reprocessing gold tailings: Integrated management approach for the control of contaminated neutral mine drainage," Minerals Engineering, vol. 187, Sept. 2022, Art. no. 107821. DOI: https://doi.org/10.1016/j.mineng.2022.107821
J. Wang, F. Faraji, J. Ramsay, and A. Ghahreman, "A review of biocyanidation as a sustainable route for gold recovery from primary and secondary low-grade resources," Journal of Cleaner Production, vol. 296, May 2021, Art. no. 126457. DOI: https://doi.org/10.1016/j.jclepro.2021.126457
E. Neag et al., "Hydrometallurgical Recovery of Gold from Mining Wastes," in Strategies of Sustainable Solid Waste Management, London, UK: IntechOpen, 2020. DOI: https://doi.org/10.5772/intechopen.94597
A. M. Tambal, A. Suliman, A. Ibrahim, E. Mohamed, and M. Kabashi, "Study of the effects of roasting and sodium thiosulfate on the extraction of silver from Volcanic Massive Sulfide ore," Results in Chemistry, vol. 5, Jan. 2023, Art. no. 100829. DOI: https://doi.org/10.1016/j.rechem.2023.100829
N. Boyabat, A. K. Özer, S. Bayrakçeken, and M. Ş. Gülaboğlu, "Thermal decomposition of pyrite in the nitrogen atmosphere," Fuel Processing Technology, vol. 85, no. 2, pp. 179–188, Feb. 2004. DOI: https://doi.org/10.1016/S0378-3820(03)00196-6
H. Li et al., "Effectiveness of microwave-assisted thermal treatment in the extraction of gold in cyanide tailings," Journal of Hazardous Materials, vol. 384, Feb. 2020, Art. no. 121456. DOI: https://doi.org/10.1016/j.jhazmat.2019.121456
O. Galtseva, S. Bordunov, A. Zhiganov, I. Plotnikova, and J. M. Li, "Technology of Gold-Containing Technogenic Raw Materials Processing Using the Electric Explosion Method," Materials Science Forum, vol. 942, pp. 30–39, 2019. DOI: https://doi.org/10.4028/www.scientific.net/MSF.942.30
I. R. Boboev, S. K. Kurbonov, and R. S. Sel’nitsyn, "Use of Thiourea Leaching During Gold-Containing Dump Treatment," Metallurgist, vol. 63, no. 5, pp. 633–641, Sept. 2019. DOI: https://doi.org/10.1007/s11015-019-00869-w
J. S. Loquero et al., "CYANanobot: Miniaturized Boat-Assisted Data Acquisition for Automated Cyanide Monitoring in Wastewater Using Optical Nano-Sensors," Engineering, Technology & Applied Science Research, vol. 12, no. 4, pp. 8990–8995, Aug. 2022. DOI: https://doi.org/10.48084/etasr.5063
Z. Shoshay, R. V. Sapinov, M. A. Sadenova, and P. S. Varbanov, "Intensification of the Process of Extracting Non-Ferrous Metals from Kazakhstani Technogenic Raw Materials," Chemical Engineering Transactions, vol. 88, pp. 1069–1074, Nov. 2021.
Kazakhstan Stock Exchange (KASE), Available online: https://kase.kz/files/emitters/KZAL/kzalp_2017_rus.pdf.
Y. Zhang, Q. Li, X. Liu, B. Xu, Y. Yang, and T. Jiang, "A Thermodynamic Analysis on the Roasting of Pyrite," Minerals, vol. 9, no. 4, Apr. 2019, Art. no. 220. DOI: https://doi.org/10.3390/min9040220
A. A. Nabiyeva, N. A. Kulenova, and S. V. Mamyachenkov, "Studying Kinetics of Arsenic Recovery from Copper Dross by Alkaline Sulfide Leaching," Materials Science Forum, vol. 946, pp. 547–551, 2019. DOI: https://doi.org/10.4028/www.scientific.net/MSF.946.547
G. M. Voldman and A. N. Zelikman, "Chemical Foundations of Processes," in Theory of Hydrometallurgical Processes, 4th ed., Moscow, Russia: Internet Engineering, 2003, pp. 94–104.
M. Bertolini, P. Duttilo, and F. Lisi, "Accounting carbon emissions from electricity generation: A review and comparison of emission factor-based methods," Applied Energy, vol. 392, Aug. 2025, Art. no 125992. DOI: https://doi.org/10.1016/j.apenergy.2025.125992
Y. Yuan, Y. Zhang, T. Liu, P. Hu, and Q. Zheng, "Optimization of microwave roasting-acid leaching process for vanadium extraction from shale via response surface methodology," Journal of Cleaner Production, vol. 234, pp. 494–502, Oct. 2019. DOI: https://doi.org/10.1016/j.jclepro.2019.06.271
A. Hapid et al., "Optimization of microwave-assisted roasting: Box-behnken design for oxidation of sulfide minerals and control of atmospheric sulfur in refractory gold ore pretreatment," Case Studies in Chemical and Environmental Engineering, vol. 10, Dec. 2024, Art. no. 100826. DOI: https://doi.org/10.1016/j.cscee.2024.100826
Downloads
How to Cite
License
Copyright (c) 2025 Ruslan Sapinov, Zhanserik Shoshay, Marzhan Sadenova, Dinara Kassymova

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain the copyright and grant the journal the right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) after its publication in ETASR with an acknowledgement of its initial publication in this journal.
