Development of Smart BZT-Cement Mortar Nanocomposites
Received: 31 July 2025 | Revised: 27 September 2025 | Accepted: 5 October 2025 | Online: 8 December 2025
Corresponding author: Layla M. Hasan
Abstract
Nano Silica Fume (NSF) is characterized by its ultrafine particle size and high pozzolanic reactivity, and it has shown great potential in enhancing the structural and functional properties of cement-based materials. In this work, NSF was incorporated into Barium-Zirconate-Titanate (BZT) cement composites to assess its influence on the dielectric, piezoelectric, and mechanical behavior of the system. The microstructural examinations revealed that the NSF addition refined the internal morphology, improved the BZT particle dispersion, and stimulated the formation of additional Calcium Silicate Hydrate (C-S-H), resulting in a denser and more uniform matrix. The dielectric measurements indicated a notable increase in relative permittivity and a reduction in dielectric loss, primarily attributed to the improved BZT interconnectivity and interfacial polarization. The incorporation of NSF also enhanced the matrix-filler bonding and electromechanical coupling, leading to higher piezoelectric coefficients and better acoustic impedance. It additionally caused a significant improvement in the compressive strength of the cement mortar compared to the unmodified BZT-cement composite. The findings indicate that NSF functions simultaneously as a microstructure modifier and a performance enhancer, thus broadening the application of BZT-cement composites for multifunctional sensing and structural health monitoring purposes.
Keywords:
Nano Silica Fume (NSF), BZT-cement composite, dielectric properties, piezoelectric behavior, microstructure, compressive strengthDownloads
References
J. Ma et al., "Composition, microstructure and electrical properties of K0.5Na0.5NbO3 ceramics fabricated by cold sintering assisted sintering," Journal of the European Ceramic Society, vol. 39, no. 4, pp. 986–993, Apr. 2019. DOI: https://doi.org/10.1016/j.jeurceramsoc.2018.11.044
J. H. Kim et al., "Preparation of CuO-doped (K,Na,Li)(Nb,Ta)O3 ceramics with a homogeneous microstructure by Two-step sintering for multilayered piezoelectric energy harvesters," Materials Letters, vol. 241, pp. 202–205, Apr. 2019. DOI: https://doi.org/10.1016/j.matlet.2019.01.083
J. Hao, W. Li, J. Zhai, and H. Chen, "Progress in high-strain perovskite piezoelectric ceramics," Materials Science and Engineering: R: Reports, vol. 135, pp. 1–57, Jan. 2019. DOI: https://doi.org/10.1016/j.mser.2018.08.001
R. Huang, Y. Zhao, and D. Yan, "(K0.5Na0.5)NbO3 lead-free ceramics with improved piezoelectricity and field-induced strain," Ceramics International, vol. 45, no. 1, pp. 1450–1454, Jan. 2019. DOI: https://doi.org/10.1016/j.ceramint.2018.09.275
P. Li et al., "High-performance potassium-sodium niobate lead-free piezoelectric ceramics based on polymorphic phase boundary and crystallographic texture," Acta Materialia, vol. 165, pp. 486–495, Feb. 2019. DOI: https://doi.org/10.1016/j.actamat.2018.12.024
W. Yang, P. Li, F. Li, X. Liu, B. Shen, and J. Zhai, "Enhanced piezoelectric performance and thermal stability of alkali niobate-based ceramics," Ceramics International, vol. 45, no. 2, Part A, pp. 2275–2280, Feb. 2019. DOI: https://doi.org/10.1016/j.ceramint.2018.10.141
Z. Dai et al., "High piezoelectricity of BiScO3-PbTiO3 ceramics prepared by two step sintering," Materials Letters, vol. 241, pp. 55–59, Apr. 2019. DOI: https://doi.org/10.1016/j.matlet.2019.01.046
L. F. Zhu et al., "Enhanced piezoelectric and ferroelectric properties of BiFeO3-BaTiO3 lead-free ceramics by optimizing the sintering temperature and dwell time," Journal of the European Ceramic Society, vol. 38, no. 10, pp. 3463–3471, Aug. 2018. DOI: https://doi.org/10.1016/j.jeurceramsoc.2018.03.044
R. Rianyoi, R. Potong, A. Ngamjarurojana, and A. Chaipanich, "Dielectric and piezoelectric properties of 2-2 connectivity lead-free piezoelectric ceramic Bi0.5Na0.5TiO3/Portland cement composites," Ceramics International, vol. 44, pp. S220–S223, Nov. 2018. DOI: https://doi.org/10.1016/j.ceramint.2018.08.110
N. Jaitanong, S. Narksitipan, A. Ngamjarurojana, and A. Chaipanich, "Influence of graphene nanoplatelets on morphological and electrical properties of silica fume blended cement – Piezoelectric ceramic composite," Ceramics International, vol. 44, pp. S137–S140, Nov. 2018. DOI: https://doi.org/10.1016/j.ceramint.2018.08.131
R. Prasad, A. E. Mahmoud, and S. K. S. Parashar, "Enhancement of electromagnetic shielding and piezoelectric properties of White Portland cement by hydration time," Construction and Building Materials, vol. 204, pp. 20–27, Apr. 2019. DOI: https://doi.org/10.1016/j.conbuildmat.2019.01.140
N. Jaitanong, R. Yimnirun, H. R. Zeng, G. R. Li, Q. R. Yin, and A. Chaipanich, "Piezoelectric properties of cement based/PVDF/PZT composites," Materials Letters, vol. 130, pp. 146–149, Sep. 2014. DOI: https://doi.org/10.1016/j.matlet.2014.05.040
T. Wittinanon, R. Rianyoi, R. Potong, and A. Chaipanich, "Effect of epoxy resin addition on the acoustic impedance, microstructure, dielectric and piezoelectric properties of 1–3 connectivity lead-free barium zirconate titanate ceramic cement-based composites," Ceramics International, vol. 50, no. 23, Part C, pp. 52144–52151, Dec. 2024. DOI: https://doi.org/10.1016/j.ceramint.2024.10.251
P. Julphunthong, P. Wiwatrojanagul, P. Tiantong, T. Bongkarn, R. Rianyoi, and R. Potong, "Development and evaluation of KNLNTS-cement composites for use as piezoelectric sensors in structural health monitoring applications," Results in Engineering, vol. 25, Mar. 2025, Art. no. 104526. DOI: https://doi.org/10.1016/j.rineng.2025.104526
R. Potong, R. Rianyoi, A. Ngamjarurojana, and A. Chaipanich, "Dielectric and piezoelectric properties of 1–3 non-lead barium zirconate titanate-Portland cement composites," Ceramics International, vol. 39, pp. S53–S57, May 2013. DOI: https://doi.org/10.1016/j.ceramint.2012.10.034
P. Chomyen, R. Potong, R. Rianyoi, A. Ngamjarurojana, P. Chindaprasirt, and A. Chaipanich, "Microstructure, dielectric and piezoelectric properties of 0–3 lead free barium zirconate titanate ceramic-Portland fly ash cement composites," Ceramics International, vol. 44, no. 1, pp. 76–82, Jan. 2018. DOI: https://doi.org/10.1016/j.ceramint.2017.09.112
W. Ding, Y. Liu, T. Shiotani, Q. Wang, N. Han, and F. Xing, "Cement-Based Piezoelectric Ceramic Composites for Sensing Elements: A Comprehensive State-of-the-Art Review," Sensors, vol. 21, no. 9, Jan. 2021, Art. no. 3230. DOI: https://doi.org/10.3390/s21093230
C. Zhuang and Y. Chen, "The effect of nano-SiO2 on concrete properties: a review," Nanotechnology Reviews, vol. 8, no. 1, pp. 562–572, Jan. 2019. DOI: https://doi.org/10.1515/ntrev-2019-0050
P. Brzozowski, J. Strzałkowski, P. Rychtowski, R. Wróbel, B. Tryba, and E. Horszczaruk, "Effect of Nano-SiO2 on the Microstructure and Mechanical Properties of Concrete under High Temperature Conditions," Materials, vol. 15, no. 1, Jan. 2022, Art. no. 166. DOI: https://doi.org/10.3390/ma15010166
F. Huang et al., "Impact of silica fume on the long-term stability of cement-based materials with low water-to-binder ratio under different curing conditions," Construction and Building Materials, vol. 450, Nov. 2024, Art. no. 138604. DOI: https://doi.org/10.1016/j.conbuildmat.2024.138604
H. M. Kamal, M. J. Kadhim, and R. K. M. Jawad, "Investigate the colloidal nano-zinc oxide addition on the strength acceleration of G-sand cement mortar," AIP Conference Proceedings, vol. 2213, no. 1, Mar. 2020, Art. no. 020148. DOI: https://doi.org/10.1063/5.0000294
"Standard Test Method for Density, Absorption, and Voids in Hardened Concrete," ASTM International, West Conshohocken, PA, Standard C642-21, Jan. 2022.
M. J. Kadhim, L. M. Hasan, and H. M. Kamal, "Investigating the effects of nano-blast furnace slag powder on the behaviour of composite cement materials," Journal of Achievements in Materials and Manufacturing Engineering, vol. 116, no. 1, pp. 5–10, Jan. 2023. DOI: https://doi.org/10.5604/01.3001.0016.3392
M. F. Qasim, Z. K. Abbas, and S. K. Abed, "Producing Green Concrete with Plastic Waste and Nano Silica Sand," Engineering, Technology & Applied Science Research, vol. 11, no. 6, pp. 7932–7937, Dec. 2021. DOI: https://doi.org/10.48084/etasr.4593
"Standard Test Method for Compressive Strength of Hydraulic Cement Mortars(Using 2-in. or [50-mm] Cube Specimens)," ASTM International, West Conshohocken, PA, Standard C109/C109M-05, Aug. 2017.
C. Shi et al., "Design and manufacture of lead-free eco-friendly cement-based piezoelectric composites achieving superior piezoelectric properties for concrete structure applications," Composites Part B: Engineering, vol. 259, Jun. 2023, Art. no. 110750. DOI: https://doi.org/10.1016/j.compositesb.2023.110750
Downloads
How to Cite
License
Copyright (c) 2025 Hamza M. Kamal, Mohammed J. Kadhim, Layla M. Hasan

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain the copyright and grant the journal the right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) after its publication in ETASR with an acknowledgement of its initial publication in this journal.
