Investigating the Impact of Fly Ash Replacement with Portland Cement on Porosity, Water Absorption, and Compressive Strength of Geopolymer Mortars in a Tidal Acid Environment

Authors

  • Ratni Nurwidayati Civil Engineering Program, Engineering Faculty, Lambung Mangkurat University, Indonesia https://orcid.org/0000-0001-7927-1206
  • Ninis Hadi Haryanti Physics Program, Mathematics, and Natural Sciences Faculty, Lambung Mangkurat University, Indonesia
  • Nursiah Chairunnisa Civil Engineering Program, Engineering Faculty, Universitas Lambung Mangkurat, Indonesia
  • Ade Yuniati Pratiwi Civil Engineering Program, Engineering Faculty, Universitas Lambung Mangkurat, Indonesia
  • Wiku Adhiwicaksana Krasna Civil Engineering Program, Engineering Faculty, Universitas Lambung Mangkurat, Indonesia
  • Nadia Rahmadania Civil Engineering Program, Engineering Faculty, Universitas Lambung Mangkurat, Indonesia
Volume: 15 | Issue: 6 | Pages: 28829-28835 | December 2025 | https://doi.org/10.48084/etasr.13667

Abstract

This study examines how Portland cement affects the physical and mechanical properties of geopolymer mortar when exposed to tidal water after 28 days of curing, when used instead of fly ash. Geopolymer, an alternative to concrete, utilizes waste materials to replace Portland cement. However, it has a relatively slow setting time. This study evaluated the influence of varying levels of Portland cement replacement on the setting time, water absorption, porosity, sorptivity, and compressive strength by replacing fly ash with Portland cement at levels of 0%, 5%, 7%, and 10%. The specimens were cured for 24 h at 100 °C after molding. After 28 days, the specimens were exposed to an artificial acidic environment with a pH of 3 for one month. The results showed that replacing fly ash with Portland cement reduced the initial and final setting times. The water absorption, porosity, and sorptivity increased as the percentage of Portland cement replacement rose, while the compressive strength of the geopolymer mortar improved with 7% and 10% Portland cement replacements.

Keywords:

acid, geopolymer, porosity, sorptivity, tidal

Downloads

Download data is not yet available.

References

A. Alsalman, L. N. Assi, R. S. Kareem, K. Carter, and P. Ziehl, "Energy and CO2 emission assessments of alkali-activated concrete and Ordinary Portland Cement concrete: A comparative analysis of different grades of concrete," Cleaner Environmental Systems, vol. 3, Dec. 2021, Art. no. 100047. DOI: https://doi.org/10.1016/j.cesys.2021.100047

R. Nurwidayati, M. B. Ulum, J. J. Ekaputri, T. Triwulan, and P. Suprobo, "Characterization of Fly Ash on Geopolymer Paste," Materials Science Forum, vol. 841, pp. 118–125, 2016. DOI: https://doi.org/10.4028/www.scientific.net/MSF.841.118

X. Dai, S. Aydin, M. Y. Yardimci, and G. De Schutter, "Early structural build-up, setting behavior, reaction kinetics and microstructure of sodium silicate-activated slag mixtures with different retarder chemicals," Cement and Concrete Research, vol. 159, Sept. 2022, Art. no. 106872. DOI: https://doi.org/10.1016/j.cemconres.2022.106872

Y. Alrefaei, Y.-S. Wang, and J.-G. Dai, "The effectiveness of different superplasticizers in ambient cured one-part alkali activated pastes," Cement and Concrete Composites, vol. 97, pp. 166–174, Mar. 2019. DOI: https://doi.org/10.1016/j.cemconcomp.2018.12.027

P. Kamhangrittirong, P. Suwanvitaya, and P. Chindaprasirt, "Synthesis and Properties of High Calcium Fly Ash Based Geopolymer for Concrete Applications," in 36th Conference on Our World in Concrete & Structures, Singapore, 2011.

P. Nath, P. K. Sarker, and V. B. Rangan, "Early Age Properties of Low-calcium Fly Ash Geopolymer Concrete Suitable for Ambient Curing," Procedia Engineering, vol. 125, pp. 601–607, Jan. 2015. DOI: https://doi.org/10.1016/j.proeng.2015.11.077

Y. Zhang, J. Yang, and X. Cao, "Effects of several retarders on setting time and strength of building gypsum," Construction and Building Materials, vol. 240, Apr. 2020, Art. no. 117927. DOI: https://doi.org/10.1016/j.conbuildmat.2019.117927

A. Kusbiantoro, M. S. Ibrahim, K. Muthusamy, and A. Alias, "Development of Sucrose and Citric Acid as the Natural based Admixture for Fly Ash based Geopolymer," Procedia Environmental Sciences, vol. 17, pp. 596–602, Jan. 2013. DOI: https://doi.org/10.1016/j.proenv.2013.02.075

S. H. Bong, B. Nematollahi, A. Nazari, M. Xia, and J. Sanjayan, "Efficiency of Different Superplasticizers and Retarders on Properties of ‘One-Part’ Fly Ash-Slag Blended Geopolymers with Different Activators," Materials, vol. 12, no. 20, Jan. 2019, Art. no. 3410. DOI: https://doi.org/10.3390/ma12203410

U. Rattanasak, K. Pankhet, and P. Chindaprasirt, "Effect of chemical admixtures on properties of high-calcium fly ash geopolymer," International Journal of Minerals, Metallurgy, and Materials, vol. 18, no. 3, pp. 364–369, June 2011. DOI: https://doi.org/10.1007/s12613-011-0448-3

P. Nath and P. K. Sarker, "Use of OPC to improve setting and early strength properties of low calcium fly ash geopolymer concrete cured at room temperature," Cement and Concrete Composites, vol. 55, pp. 205–214, Jan. 2015. DOI: https://doi.org/10.1016/j.cemconcomp.2014.08.008

L. N. Assi, E. Deaver, and P. Ziehl, "Using sucrose for improvement of initial and final setting times of silica fume-based activating solution of fly ash geopolymer concrete," Construction and Building Materials, vol. 191, pp. 47–55, Dec. 2018. DOI: https://doi.org/10.1016/j.conbuildmat.2018.09.199

Y. Zhang, W. Liu, and M. Liu, "Setting time and mechanical properties of chemical admixtures modified FA/GGBS-based engineered geopolymer composites," Construction and Building Materials, vol. 431, p. 136473, June 2024. DOI: https://doi.org/10.1016/j.conbuildmat.2024.136473

M. Shaaban, O. F. Hussien, and S. Khalifa, "Characteristics and Microstructure of Geopolymer Mortars incorporating Ground Granulated Blast Furnace Slag and Calcined Dolomite Powder: A Sustainable Solution for Construction Materials," Engineering, Technology & Applied Science Research, vol. 15, no. 2, pp. 21791–21799, Apr. 2025. DOI: https://doi.org/10.48084/etasr.10095

M. Askarian, Z. Tao, G. Adam, and B. Samali, "Mechanical properties of ambient cured one-part hybrid OPC-geopolymer concrete," Construction and Building Materials, vol. 186, pp. 330–337, Oct. 2018. DOI: https://doi.org/10.1016/j.conbuildmat.2018.07.160

A. M. Kaja, A. Lazaro, and Q. L. Yu, "Effects of Portland cement on activation mechanism of class F fly ash geopolymer cured under ambient conditions," Construction and Building Materials, vol. 189, pp. 1113–1123, Nov. 2018. DOI: https://doi.org/10.1016/j.conbuildmat.2018.09.065

A. Mehta and R. Siddique, "Properties of low-calcium fly ash based geopolymer concrete incorporating OPC as partial replacement of fly ash," Construction and Building Materials, vol. 150, pp. 792–807, Sept. 2017. DOI: https://doi.org/10.1016/j.conbuildmat.2017.06.067

F. N. Okoye, S. Prakash, and N. B. Singh, "Durability of fly ash based geopolymer concrete in the presence of silica fume," Journal of Cleaner Production, vol. 149, pp. 1062–1067, Apr. 2017. DOI: https://doi.org/10.1016/j.jclepro.2017.02.176

M. A. M. Ariffin, M. A. R. Bhutta, M. W. Hussin, M. Mohd Tahir, and N. Aziah, "Sulfuric acid resistance of blended ash geopolymer concrete," Construction and Building Materials, vol. 43, pp. 80–86, June 2013. DOI: https://doi.org/10.1016/j.conbuildmat.2013.01.018

V. Sata, A. Sathonsaowaphak, and P. Chindaprasirt, "Resistance of lignite bottom ash geopolymer mortar to sulfate and sulfuric acid attack," Cement and Concrete Composites, vol. 34, no. 5, pp. 700–708, May 2012. DOI: https://doi.org/10.1016/j.cemconcomp.2012.01.010

S. Thokchom, P. Ghosh, and S. Ghosh, "Resistance of Fly Ash Based Geopolymer Mortars in Sulfuric Acid," ARPN Journal of Engineering and Applied Sciences, vol. 4, no. 1, pp. 65–70, Feb. 2009.

I. T. Wicaksono and R. Nurwidayati, "The Effect of pH Water on the Concrete Mixtures and Curing Condition on the Compressive Strength of Concrete," IOP Conference Series: Earth and Environmental Science, vol. 999, no. 1, Nov. 2022, Art. no. 012006. DOI: https://doi.org/10.1088/1755-1315/999/1/012006

L. Jiang and D. Niu, "Study of deterioration of concrete exposed to different types of sulfate solutions under drying-wetting cycles," Construction and Building Materials, vol. 117, pp. 88–98, Aug. 2016. DOI: https://doi.org/10.1016/j.conbuildmat.2016.04.094

C618-02 Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use as a Mineral Admixture in Concrete. West Conshohocken, PA, USA: ASTM International, 2010.

C642-21 Standard Test Method for Density, Absorption, and Voids in Hardened Concrete. West Conshohocken, PA, USA: ASTM International, 2006.

C1585-20 Standard Test Method for Measurement of Rate of Absorption of Water by Hydraulic-Cement Concretes. West Conshohocken, PA, USA: ASTM International, 2013.

C191-21 Standard Test Methods for Time of Setting of Hydraulic Cement by Vicat Needle. West Conshohocken, PA, USA: ASTM International, 2008.

W. Huo, Z. Zhu, J. Zhang, Z. Kang, S. Pu, and Y. Wan, "Utilization of OPC and FA to enhance reclaimed lime-fly ash macadam based geopolymers cured at ambient temperature," Construction and Building Materials, vol. 303, Oct. 2021, Art. no. 124378. DOI: https://doi.org/10.1016/j.conbuildmat.2021.124378

H. E. Elyamany, A. E. M. Abd Elmoaty, and A. M. Elshaboury, "Setting time and 7-day strength of geopolymer mortar with various binders," Construction and Building Materials, vol. 187, pp. 974–983, Oct. 2018. DOI: https://doi.org/10.1016/j.conbuildmat.2018.08.025

T. Phoo-ngernkham, P. Chindaprasirt, V. Sata, S. Pangdaeng, and T. Sinsiri, "Properties of high calcium fly ash geopolymer pastes with Portland cement as an additive," International Journal of Minerals, Metallurgy, and Materials, vol. 20, no. 2, pp. 214–220, Feb. 2013. DOI: https://doi.org/10.1007/s12613-013-0715-6

T. Suwan and M. Fan, "Influence of OPC replacement and manufacturing procedures on the properties of self-cured geopolymer," Construction and Building Materials, vol. 73, pp. 551–561, Dec. 2014. DOI: https://doi.org/10.1016/j.conbuildmat.2014.09.065

M. S. Saif, M. O. R. El-Hariri, A. I. Sarie-Eldin, B. A. Tayeh, and M. F. Farag, "Impact of Ca+ content and curing condition on durability performance of metakaolin-based geopolymer mortars," Case Studies in Construction Materials, vol. 16, June 2022, Art. no. e00922. DOI: https://doi.org/10.1016/j.cscm.2022.e00922

P. Nath and P. K. Sarker, "Effect of GGBFS on setting, workability and early strength properties of fly ash geopolymer concrete cured in ambient condition," Construction and Building Materials, vol. 66, pp. 163–171, Sept. 2014. DOI: https://doi.org/10.1016/j.conbuildmat.2014.05.080

S. Yaseri, V. Masoomi Verki, and M. Mahdikhani, "Utilization of high volume cement kiln dust and rice husk ash in the production of sustainable geopolymer," Journal of Cleaner Production, vol. 230, pp. 592–602, Sept. 2019. DOI: https://doi.org/10.1016/j.jclepro.2019.05.056

D. Hardjito, C. Cheak, and C. L. Ing, "Strength and Setting Times of Low Calcium Fly Ash-based Geopolymer Mortar," Modern Applied Science, vol. 2, no. 4, July 2008, Art. no. p3. DOI: https://doi.org/10.5539/mas.v2n4p3

C. Chotetanorm, P. Chindaprasirt, V. Sata, S. Rukzon, and A. Sathonsaowaphak, "High-Calcium Bottom Ash Geopolymer: Sorptivity, Pore Size, and Resistance to Sodium Sulfate Attack," Journal of Materials in Civil Engineering, vol. 25, no. 1, pp. 105–111, Jan. 2013. DOI: https://doi.org/10.1061/(ASCE)MT.1943-5533.0000560

C. K. Yip, G. C. Lukey, J. L. Provis, and J. S. J. van Deventer, "Effect of calcium silicate sources on geopolymerisation," Cement and Concrete Research, vol. 38, no. 4, pp. 554–564, Apr. 2008. DOI: https://doi.org/10.1016/j.cemconres.2007.11.001

F. Xie, J. Li, G. Zhao, C. Wang, Y. Wang, and P. Zhou, "Experimental investigations on the durability and degradation mechanism of cast-in-situ recycled aggregate concrete under chemical sulfate attack," Construction and Building Materials, vol. 297, Aug. 2021, Art. no. 123771. DOI: https://doi.org/10.1016/j.conbuildmat.2021.123771

Downloads

How to Cite

[1]
R. Nurwidayati, N. H. Haryanti, N. Chairunnisa, A. Y. Pratiwi, W. A. Krasna, and N. Rahmadania, “Investigating the Impact of Fly Ash Replacement with Portland Cement on Porosity, Water Absorption, and Compressive Strength of Geopolymer Mortars in a Tidal Acid Environment”, Eng. Technol. Appl. Sci. Res., vol. 15, no. 6, pp. 28829–28835, Dec. 2025.

Metrics

Abstract Views: 287
PDF Downloads: 224

Metrics Information