A Comparison of TiC Wetting Angles with Low Carbon Steel by Contact and Noncontact Methods

Authors

  • Andrey Anikeev Zlatoust Branch, South Ural State University (National Research University), Zlatoust, Russia
  • Ilya Chumanov Zlatoust Branch, South Ural State University (National Research University), Zlatoust, Russia
  • Abdrakhman Naizabekov Rudny Industrial University, Rudny, Kazakhstan
  • Sergey Lezhnev Rudny Industrial University, Rudny, Kazakhstan
  • Evgeniy Panin Karaganda Industrial University, Temirtau, Kazakhstan
Volume: 15 | Issue: 4 | Pages: 25221-25227 | August 2025 | https://doi.org/10.48084/etasr.12025

Abstract

This study investigates the kinetics of the high-temperature interaction between titanium carbide (TiC) and a low-carbon melt in an argon atmosphere, as well as the microstructure of the resulting substrate surface. A key feature of this work is the comparative analysis of two experimental techniques, contact and noncontact, to study the interaction between reinforcing particles and metal. This methodological approach highlights significant discrepancies in the results obtained by each technique, which is critical to optimizing processes in the fabrication of gradient materials, where reliable metal bonding is essential. The analysis showed that, under contact conditions, iron droplets enriched with titanium and carbon formed across the plate surface. In contrast, under noncontact conditions, droplet formation was minimal, and the metal was entirely absorbed into the substrate.

Keywords:

kinetics of high-temperature interaction, contact and non-contact heating, wetting angle, titanium carbide

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References

V. P. Vijeesh, M. R. Ramesh, and A. D. Anoop, "Inconel 625 Coatings on AISI 304 Steel using Laser Cladding: Microstructure and Hardness," Engineering, Technology & Applied Science Research, vol. 13, no. 5, pp. 11911–11916, Oct. 2023. DOI: https://doi.org/10.48084/etasr.6297

B. Pace et al., "Tuning Ta coating properties through chemical and plasma etching pre-treatment of NiTi wire substrates," Surface and Coatings Technology, vol. 418, Jul. 2021, Art. no. 127214. DOI: https://doi.org/10.1016/j.surfcoat.2021.127214

R. Saeedi, R. Shoja Razavi, S. R. Bakhshi, M. Erfanmanesh, and A. Ahmadi Bani, "Optimization and characterization of laser cladding of NiCr and NiCr–TiC composite coatings on AISI 420 stainless steel," Ceramics International, vol. 47, no. 3, pp. 4097–4110, Feb. 2021. DOI: https://doi.org/10.1016/j.ceramint.2020.09.284

I. Shishkovsky, N. Kakovkina, and V. Scherbakov, "Fabrication of heat-resisting nickel composite gradient structures with TiC nano additive during powder bed fusion process," Procedia CIRP, vol. 74, pp. 68–71, 2018. DOI: https://doi.org/10.1016/j.procir.2018.08.032

S. Yang, N. Chen, W. Liu, M. Zhong, Z. Wang, and H. Kokawa, "Fabrication of nickel composite coatings reinforced with TiC particles by laser cladding," Surface and Coatings Technology, vol. 183, no. 2–3, pp. 254–260, May 2004. DOI: https://doi.org/10.1016/j.surfcoat.2003.09.062

F. Qiu et al., "Application of nanoparticles in cast steel: An overview," China Foundry, vol. 17, no. 2, pp. 111–126, Mar. 2020. DOI: https://doi.org/10.1007/s41230-020-0037-z

S. Jiang et al., "Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation," Nature, vol. 544, no. 7651, pp. 460–464, Apr. 2017. DOI: https://doi.org/10.1038/nature22032

S. H. Kim et al., "Heat treatment response of TiC-reinforced steel matrix composite," Metals and Materials International, vol. 22, no. 5, pp. 935–941, Sep. 2016. DOI: https://doi.org/10.1007/s12540-016-6176-5

B. X. Dong et al., "Design of TiC nanoparticles and their morphology manipulating mechanisms by stoichiometric ratios: Experiment and first-principle calculation," Materials & Design, vol. 181, Nov. 2019, Art. no. 107951. DOI: https://doi.org/10.1016/j.matdes.2019.107951

X. Sun, J. Kang, and Q. Yong, "Revealing the difference of precipitation kinetics between TiC and VC in low-carbon tempered martensitic steels," Journal of Materials Science, vol. 55, no. 33, pp. 16018–16032, Nov. 2020. DOI: https://doi.org/10.1007/s10853-020-05176-3

I. Kayabasi, G. Sur, H. Gokkaya, and Y. Sun, "Functionally Graded Material Production and Characterization using the Vertical Separator Molding Technique and the Powder Metallurgy Method," Engineering, Technology & Applied Science Research, vol. 12, no. 4, pp. 8785–8790, Aug. 2022. DOI: https://doi.org/10.48084/etasr.5025

C. Zhang et al., "Additive manufacturing of functionally graded materials: A review," Materials Science and Engineering: A, vol. 764, Sep. 2019, Art. no. 138209. DOI: https://doi.org/10.1016/j.msea.2019.138209

S. A. Guzenkov, D. N. Fedorov, D. V. Rutskii, and S. B. Gamanyuk, "Increasing the structural strength of cast steel by powder modification," Steel in Translation, vol. 40, no. 3, pp. 294–297, Mar. 2010. DOI: https://doi.org/10.3103/S096709121003023X

E. V. Protopopov, V. P. Komshukov, L. A. Ganzer, and D. B. Foigt, "Promising technologies for metal modification with nanopowder inoculators," Chernaya Metallurgiya = Izvestiya. Ferrous Metallurgy, vol. 6, pp. 39–43, Jun. 2011.

E. V. Protopopov, Yu. A. Seleznev, A. N. Cherepanov, D. V. Foigt, R. S. Aizatylov, and L. A. Ganzer, "Metal modification with nanopowder materials for the quality of slab continuous casting improvement," Izvestiya Visshikh Uchebnykh Zavedenii. Chernaya Metallurgiya = Izvestiya. Ferrous Metallurgy, vol. 56, no. 12, pp. 8-11, Mar. 2015. DOI: https://doi.org/10.17073/0368-0797-2013-12-8-11

E. V. Protopopov, Yu. A. Seleznev, A. N. Cherepanov, D. V. Foigt, R. S. Aizatulov, and L. A. Ganzer, "Nanopowder modification of metals to improve continuous-cast slab," Steel in Translation, vol. 43, no. 12, pp. 773–776, Dec. 2013. DOI: https://doi.org/10.3103/S0967091213120139

E. V. Protopopov, Yu. A. Seleznev, A. N. Cherepanov, V. Ya. Chinokalov, D. V. Foigt, and L. A. Ganzer, "Modifying metal with nanopowder in a continuous bar-casting machine," Steel in Translation, vol. 43, no. 6, pp. 341–343, Jun. 2013. DOI: https://doi.org/10.3103/S0967091213060168

S. N. Zherebtsov, S. N. Mikhailets, I. V. Zabegailo, and E. A. Rogachev, "Use of Centrifugal Electroslag Casting for Producing Cold-Resistant Steel Grade Ring Blanks of Flange Objects," Chemical and Petroleum Engineering, vol. 53, no. 5–6, pp. 347–352, Sep. 2017. DOI: https://doi.org/10.1007/s10556-017-0346-2

S. N. Zherebtsov and A. B. Korostelev, "Electroslag remelting of the metal wastes of nickel alloys," Russian Metallurgy (Metally), vol. 2012, no. 6, pp. 548–551, Jun. 2012. DOI: https://doi.org/10.1134/S0036029512060237

S. L. Lu, F. R. Xiao, S. J. Zhang, Y. W. Mao, and B. Liao, "Simulation study on the centrifugal casting wet-type cylinder liner based on ProCAST," Applied Thermal Engineering, vol. 73, no. 1, pp. 512–521, Dec. 2014. DOI: https://doi.org/10.1016/j.applthermaleng.2014.07.073

S. Lu, F. Xiao, Z. Guo, L. Wang, H. Li, and B. Liao, "Numerical simulation of multilayered multiple metal cast rolls in compound casting process," Applied Thermal Engineering, vol. 93, pp. 518–528, Jan. 2016. DOI: https://doi.org/10.1016/j.applthermaleng.2015.09.114

N. J. Humphreys et al., "Modelling and validation: Casting of Al and TiAl alloys in gravity and centrifugal casting processes," Applied Mathematical Modelling, vol. 37, no. 14–15, pp. 7633–7643, Aug. 2013. DOI: https://doi.org/10.1016/j.apm.2013.03.030

N. J. Humphreys, D. McBride, T. N. Croft, D. M. Shevchenko, N. R. Green, and M. Cross, "Modeling of Centrifugal Casting Processes with Complex Geometries," in CFD Modeling and Simulation in Materials Processing, 1st ed., L. Nastac, L. Zhang, B. G. Thomas, A. Sabau, N. El‐Kaddah, A. C. Powell, and H. Combeau, Eds. Wiley, 2012, pp. 187–196. DOI: https://doi.org/10.1002/9781118364697.ch22

S. Sen, S. Reddy, B. K. Muralidhara, and P. G. Mukunda, "Study of Flow Behaviour in Vertical Centrifugal Casting," Materials Today: Proceedings, vol. 24, pp. 1392–1399, 2020. DOI: https://doi.org/10.1016/j.matpr.2020.04.457

B. Balout and J. Litwin, "Mathematical Modeling of Particle Segregation During Centrifugal Casting of Metal Matrix Composites," Journal of Materials Engineering and Performance, vol. 21, no. 4, pp. 450–462, Apr. 2012. DOI: https://doi.org/10.1007/s11665-011-9873-8

N. Song, Y. Luan, Y. Bai, Z. A. Xu, X. Kang, and D. Li, "Numerical Simulation of Solidification of Work Roll in Centrifugal Casting Process," Journal of Materials Science & Technology, vol. 28, no. 2, pp. 147–154, Feb. 2012. DOI: https://doi.org/10.1016/S1005-0302(12)60035-8

J. T. O. Florenciano, A. Ambrosi, D. Hotza, and S. Y. G. González, "Understanding centrifugal casting in the manufacture of functionally graded materials," Journal of the European Ceramic Society, vol. 42, no. 15, pp. 7089–7101, Dec. 2022. DOI: https://doi.org/10.1016/j.jeurceramsoc.2022.08.042

J. Bohacek, A. Kharicha, A. Ludwig, and M. Wu, "Simulation of Horizontal Centrifugal Casting: Mold Filling and Solidification," ISIJ International, vol. 54, no. 2, pp. 266–274, 2014. DOI: https://doi.org/10.2355/isijinternational.54.266

J. Yin, "Numerical modelling of centrifugal casting process," M.S. Thesis, KTH, Stockholm, Sweden, 2016.

N. Sobczak, R. Nowak, W. Radziwill, J. Budzioch, and A. Glenz, "Experimental complex for investigations of high temperature capillarity phenomena," Materials Science and Engineering: A, vol. 495, no. 1–2, pp. 43–49, Nov. 2008. DOI: https://doi.org/10.1016/j.msea.2007.11.094

M. Malaki, A. Fadaei Tehrani, B. Niroumand, and M. Gupta, "Wettability in Metal Matrix Composites," Metals, vol. 11, no. 7, Jun. 2021, Art. no. 1034. DOI: https://doi.org/10.3390/met11071034

C. Xuan, H. Shibata, Z. Zhao, P. G. Jönsson, and K. Nakajima, "Wettability of TiN by Liquid Iron and Steel," ISIJ International, vol. 55, no. 8, pp. 1642–1651, 2015. DOI: https://doi.org/10.2355/isijinternational.ISIJINT-2014-819

W. Fu et al., "Wetting and interfacial behavior of Sn–Ti alloys on zirconia," Journal of Materials Science, vol. 54, no. 1, pp. 812–822, Jan. 2019. DOI: https://doi.org/10.1007/s10853-018-2829-8

Q. Zeng, B. Wang, and Z. Guo, "Recent advances in microfluidics by tuning wetting behaviors," Materials Today Physics, vol. 40, Jan. 2024, Art. no. 101324. DOI: https://doi.org/10.1016/j.mtphys.2023.101324

D. V. Sergeev, A. N. Anikeev, and I. V. Chumanov, "A study of the products reaction titanium carbide and low-carbon tungsten-containing steel in the oxidative atmosphere," in Physics, Technologies and Innovation (PTI-2018): Proceedings of the V International Young Researchers’ Conference, Ekaterinburg, Russia, 2018, Art. no. 020093. DOI: https://doi.org/10.1063/1.5055166

M. Kiviö, L. Holappa, S. Louhenkilpi, M. Nakamoto, and T. Tanaka, "Studies on Interfacial Phenomena in Titanium Carbide/Liquid Steel Systems for Development of Functionally Graded Material," Metallurgical and Materials Transactions B, vol. 47, no. 4, pp. 2114–2122, Aug. 2016. DOI: https://doi.org/10.1007/s11663-016-0658-1

Q. Lin and R. Sui, "Wetting of carbide ceramics (B4C, SiC, TiC and ZrC) by molten Ni at 1753 K," Journal of Alloys and Compounds, vol. 649, pp. 505–514, Nov. 2015. DOI: https://doi.org/10.1016/j.jallcom.2015.07.138

I. V. Chumanov, V. I. Chumanov, and A. N. Anikeev, "Preparation of precipitation-strengthened hollow billets for rotary dispersers," Metallurgist, vol. 55, no. 5–6, pp. 439–443, Sep. 2011. DOI: https://doi.org/10.1007/s11015-011-9449-8

A. N. Anikeev, I. V. Chumanov, I. A. Alekseev, and V. V. Sedukhin, "Calculation of Cutting Conditions, Including the Estimation of the Machinability of Experimental Samples of Centrifugally Cast Precipitation-Hardened Metallic Materials," Russian Metallurgy (Metally), vol. 2021, no. 12, pp. 1517–1523, Dec. 2021. DOI: https://doi.org/10.1134/S003602952112003X

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[1]
A. Anikeev, I. Chumanov, A. Naizabekov, S. Lezhnev, and E. Panin, “A Comparison of TiC Wetting Angles with Low Carbon Steel by Contact and Noncontact Methods”, Eng. Technol. Appl. Sci. Res., vol. 15, no. 4, pp. 25221–25227, Aug. 2025.

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