Development of a Green Corrosion Inhibitor from Lophatherum Gracile Extract for Steel Protection

Authors

  • Muhammad Imran Haris Department of Civil Engineering, Faculty of Engineering, Hasanuddin University, Makassar, South Sulawesi, Indonesia
  • Agung Department of Civil Engineering, Faculty of Engineering, Hasanuddin University, Makassar, South Sulawesi, Indonesia
  • Muhammad Anjas Department of Civil Engineering, Faculty of Engineering, Hasanuddin University, Makassar, South Sulawesi, Indonesia
  • Geraldy Juniarto Billy Houston Department of Civil Engineering, Faculty of Engineering, Hasanuddin University, Makassar, South Sulawesi, Indonesia
  • Nurul Qadry Department of Biology, Faculty of Mathematics and Natural Science, Hasanuddin University, Makassar, South Sulawesi, Indonesia
  • Fakhruddin Department of Civil Engineering, Faculty of Engineering, Hasanuddin University, Makassar, South Sulawesi, Indonesia
Volume: 15 | Issue: 1 | Pages: 19253-19260 | February 2025 | https://doi.org/10.48084/etasr.8609

Abstract

Corrosion constitutes a significant challenge in the context of infrastructure development, with particular implications for steel materials. One common method for preventing corrosion is the application of inhibitor materials. Inhibitors are classified into two main categories: organic inhibitors and inorganic inhibitors. Inorganic inhibitors are costly and may have adverse environmental effects. Consequently, organic inhibitors that are cost-effective and environmentally benign were developed. One plant that has the potential to be used as an organic inhibitor is Lophatherum gracile B. (Lophatherum gracile Brogn), due to its antioxidant compounds that can prevent corrosion. The objective of this research is to analyze the effect of the Lophatherum gracile B. extract inhibitor on the corrosion rate and its inhibition efficiency on reinforcing steel. The weight loss method was employed to determine the corrosion rate in a 3% sodium chloride (NaCl) medium, with concentration variations of 0%, 2%, and 4% over a duration of 24, 72, and 96 hours. The findings indicated that the lowest corrosion rate was observed at the 4% concentration, while the highest rate was noted at the 0% concentration. The inhibition efficiency of the Lophatherum gracile B. extract was determined to be greater than 66%. The qualitative analysis of the macro photo material structure indicated that the steel surface treated with Lophatherum gracile B. extract exhibited a reduced level of corrosion in comparison to the control sample. Furthermore, the tensile strength testing demonstrated that the decline in the tensile strength of steel could be attenuated through the use of inhibitors. These findings suggest that the Lophatherum gracile B. extract is an effective inhibitor material for reinforcing steel.

Keywords:

Lophatherum gracile, corrosion, coating, inhibitor

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References

S. Singthanu and T. Nilsonthi, "A Comparative Study of the Oxidation Behavior of Hot-Rolled Steel established from Medium and Thin Slabs oxidized in 20% H2O-N2 at 600-900°C," Engineering, Technology & Applied Science Research, vol. 14, no. 1, pp. 12646–12651, Feb. 2024.

C. Zeng, Z. Zheng, H. Zhang, Y. Huang, X. Wang, and G. Liu, "3D mesoscale investigation of non-uniform steel corrosion in reinforced concrete under chloride environments," Construction and Building Materials, vol. 411, Jan. 2024, Art. no. 134273.

P. Liu, Q.-H. Zhang, Y. Watanabe, T. Shoji, and F.-H. Cao, "A critical review of the recent advances in inclusion-triggered localized corrosion in steel," NPJ Materials Degradation, vol. 6, no. 1, pp. 1–17, Sep. 2022.

R. Camaratta et al., "Electrodeposition of organic corrosion inhibitor prepared from eucalyptus robusta leaves," Journal of Building Engineering, vol. 94, Oct. 2024, Art. no. 109944.

S. B. Ulaeto, R. P. Ravi, I. I. Udoh, G. M. Mathew, and T. P. D. Rajan, "Polymer-Based Coating for Steel Protection, Highlighting Metal–Organic Framework as Functional Actives: A Review," Corrosion and Materials Degradation, vol. 4, no. 2, pp. 284–316, Jun. 2023.

V. P. Vijeesh, M. R. Ramesh, and A. D. Anoop, "Inconel 625 Coatings on AISI 304 Steel using Laser Cladding: Microstructure and Hardness," Engineering, Technology & Applied Science Research, vol. 13, no. 5, pp. 11911–11916, Oct. 2023.

P. D. Desai, C. B. Pawar, M. S. Avhad, and A. P. More, "Corrosion inhibitors for carbon steel: A review," Vietnam Journal of Chemistry, vol. 61, no. 1, pp. 15–42, 2023.

Shehnazdeep and B. Pradhan, "A study on effectiveness of inorganic and organic corrosion inhibitors on rebar corrosion in concrete: A review," Materials Today: Proceedings, vol. 65, pp. 1360–1366, Jan. 2022.

P. Li et al., "Enhancing corrosion resistance of magnesium alloys via combining green chicory extracts and metal cations as organic-inorganic composite inhibitor," Corrosion Communications, vol. 9, pp. 44–56, Mar. 2023.

J.-H. Zheng, S.-X. Lin, X.-Y. Li, C.-Y. Shen, S.-W. Zheng, and W.-B. Chen, "Flavonoids from Lophatherum gracile Brongn. Ameliorate Liver Damages in High-Fat Diet and Streptozotocin-Induced Diabetic Mice by Regulating PI3K/AKT and NF-Kappa B Pathways," Journal of Food Biochemistry, vol. 2023, no. 1, 2023, Art. no. 5273349.

Z. Li et al., "Lophatherum gracile Brongn.: A review on phytochemistry, bioactivity and food applications," Food Chemistry Advances, vol. 4, Jun. 2024, Art no.100688.

Y. Cheng et al., "Bamboo leaf: A review of traditional medicinal property, phytochemistry, pharmacology, and purification technology," Journal of Ethnopharmacology, vol. 306, Apr. 2023, Art. no. 116166.

T. Sithuba et al., "Corrosion inhibitory potential of selected flavonoid derivatives: Electrochemical, molecular⋅⋅⋅Zn surface interactions and quantum chemical approaches," Results in Engineering, vol. 16, Dec. 2022, Art. no. 100694.

V. Vorobyova, O. Sikorsky, M. Skiba, and G. Vasyliev, "Quebracho tannin as corrosion inhibitor in neutral media and novel rust conversion agent for enhanced corrosion protection," South African Journal of Chemical Engineering, vol. 44, pp. 68–80, Apr. 2023.

SNI 2052:2017 Baja tulangan beton. Badan Standardisasi Nasional, 2017.

B. Hamzah et al., "Determination of thick tannine extract levels of Guava leaves (Psidium guajava L.) by using acetone solution, ethanol, and methanol," AIP Conference Proceedings, vol. 3058, no. 1, Apr. 2024, Art. no. 050009.

G. N. Manjesh et al., "Diversity of flavonoids profile in sexually dimorphic clones of betle vine [Piper betle L.] genotypes based on liquid chromatography-mass spectrometry [LCMS/MS]," Industrial Crops and Products, vol. 187, Nov. 2022, Art. no. 115363.

R. W. Sari, E. G. Suka, and P. K. Karo, "Ekstrak Daun Sawo (Manilkara Zapota L) Sebagai Inhibitor Terhadap Laju Korosi Baja AISI 1018 Dalam Medium Korosif NaCl 3%," Journal of Energy, Material, and Instrumentation Technology, vol. 3, no. 1, Feb. 2022.

SNI 8389:2017 Cara uji tarik logam. Badan Standardisasi Nasional, 2017.

I. Alenezi, "Effects of Heat Treatment on the Corrosion Behavior of ASTM A-36 Steel," Engineering, Technology & Applied Science Research, vol. 10, no. 1, pp. 5320–5324, Feb. 2020.

G 31-72 Standard Practice for Laboratory Immersion Corrosion Testing of Metals. ASTM International, 2020.

A. Krishnan and A. S. B. Packirisamy, "Exploration of therapeutic potential and pesticidal activity of Sapindus mukorossi by In vitro and Insilico profiling of phytochemicals," Journal of Molecular Structure, vol. 1315, Nov. 2024, Art. no. 138866.

Ş. S. Çatav, E. Çetin, E. Vural, and B. Bürün, "Boron toxicity tolerance in barley may be related to intrinsically higher levels of reactive oxygen species in the shoots," Botanica Serbica, vol. 47, no. 1, pp. 113–124, Apr. 2023.

J. E. Mbosso Teinkela et al., "Evaluation of in vitro antiplasmodial, antiproliferative activities, and in vivo oral acute toxicity of Spathodea campanulata flowers," Scientific African, vol. 21, Sep. 2023, Art. no. e01871.

Y.-L. Ma et al., "In vitro digestibility and hepato-protective potential of Lophatherum gracile Brongn. leave extract," Food Chemistry, vol. 433, Feb. 2024, Art. no. 137336.

J. Chen, L. Zhang, P. Zhao, G. Ma, Q. Li, and X. Yu, "Synthesized alkyl ferulates with different chain lengths inhibited the formation of lipid oxidation products in soybean oil during deep frying," Food Chemistry, vol. 410, Jun. 2023, Art. no. 135458.

X. Sun et al., "Synthesis, characterization, and the antioxidant activity of the acetylated chitosan derivatives containing sulfonium salts," International Journal of Biological Macromolecules, vol. 152, pp. 349–358, Jun. 2020.

S. Bilgiç, "Plant extracts as corrosion inhibitors for mild steel in H2SO4 and H3PO4 media – Review II," International Journal of Corrosion and Scale Inhibition, vol. 11, no. 1, pp. 1–42, 2022.

M. A. Chowdhury, N. Hossain, M. M. S. Ahmed, M. A. Islam, S. Islam, and M. M. Rana, "Green tea and tulsi extracts as efficient green corrosion inhibitor for aluminum alloy in alkaline medium," Heliyon, vol. 9, no. 6, Jun. 2023, Art. no. e16504.

H. M. C. Abubakr, M. E. Ghaith, A. A. El-Sherif, and M. S. El-Deab, "Influence of metal ions on cysteine as a corrosion inhibitor for low carbon steel in sulfuric acid: Polarization, EIS, XPS, and DFT analysis," International Journal of Electrochemical Science, vol. 19, no. 7, Jul. 2024, Art. no. 100620.

A. Dantas et al., "A methodology to evaluate seawater corrosion on quasi-static tensile properties of a structural steel," Engineering Failure Analysis, vol. 164, Oct. 2024, Art. no. 108613.

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How to Cite

[1]
Haris, M.I., Agung, ., Anjas, M., Houston, G.J.B., Qadry, N. and Fakhruddin, . 2025. Development of a Green Corrosion Inhibitor from Lophatherum Gracile Extract for Steel Protection. Engineering, Technology & Applied Science Research. 15, 1 (Feb. 2025), 19253–19260. DOI:https://doi.org/10.48084/etasr.8609.

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