Magnesium Oxide (MgO) as a Sustainable Catalyst for Biodiesel Production from Waste Cooking Oil: A Comparative Study with KOH
Received: 13 February 2024 | Revised: 26 February 2024 | Accepted: 2 March 2024 | Online: 2 April 2024
Corresponding author: Aboulbaba Eladeb
Abstract
The present study investigates the efficiency of magnesium oxide (MgO) as a heterogeneous catalyst in the production of biodiesel from waste cooking oil (WCO), putting an emphasis on its environmental benefits, cost-effectiveness, and operational efficacy. Through a series of experiments, we optimized the reaction conditions, including catalyst concentration, reaction temperature, and ethanol to WCO molar ratio, to achieve a high biodiesel yield. The results indicate that an optimal MgO concentration of 3 wt%, a reaction temperature of 65 °C, and a molar ratio of 9:1 result in the highest biodiesel production efficiency. Additionally, MgO demonstrated significant reusability without a decrease in performance, underscoring its economic and environmental advantages. Comparative analysis revealed that MgO outperforms conventional KOH catalysts in terms of yield, purity, and sustainability. Our study suggests future research directions, including the optimization of MgO preparation methods and the exploration of co-catalyst systems to further enhance biodiesel production from WCO. This research contributes to the development of sustainable biodiesel production methods, aligning with global energy and environmental goals.
Keywords:
biodiesel, WCO, MgO, transesterificationDownloads
References
A. A. Khaskheli, G. D. Walasai, A. S. Jamali, Q. B. Jamali, Z. A. Siyal, and A. Mengal, "Performance Evaluation of Locally-Produced Waste Cooking Oil Biodiesel with Conventional Diesel Fuel," Engineering, Technology & Applied Science Research, vol. 8, no. 6, pp. 3521–3524, Dec. 2018.
A. H. Ulukardesler, "Biodiesel Production from Waste Cooking Oil Using Different Types of Catalysts," Processes, vol. 11, no. 7, Jul. 2023, Art. no. 2035.
D. H. Park, F. I. Nana, and H. M. Cho, "A Review of the Emission, Performance, Combustion, and Optimization Parameters in the Production of Biodiesel from Waste Cooking Oil," Automotive Experiences, vol. 5, no. 3, pp. 371–388, Jun. 2022.
Monika, S. Banga, and V. V. Pathak, "Biodiesel production from waste cooking oil: A comprehensive review on the application of heterogenous catalysts," Energy Nexus, vol. 10, Jun. 2023, Art. no. 100209.
M. M. Tunio, M. R. Luhur, Z. M. Ali, and U. Daher, "Performance and Emission Analysis of a Diesel Engine Using Linseed Biodiesel Blends," Engineering, Technology & Applied Science Research, vol. 8, no. 3, pp. 2958–2962, Jun. 2018.
A. Eladeb, A. Aydi, and I. Alenezi, "Ethanolysis of Waste Cooking Oils Using KOH Catalyst," Oriental Journal of Chemistry, vol. 37, no. 6, pp. 1344–1349, Dec. 2021.
W. Widayat et al., "Preparation of MgO-CaO/SiO2 catalyst from dolomite and geothermal solid waste for biodiesel production," International Journal of Renewable Energy Development, vol. 12, no. 3, pp. 541–549, May 2023.
K. A. V. Miyuranga, U. S. P. R. Arachchige, T. M. M. Marso, and G. Samarakoon, "Biodiesel Production through the Transesterification of Waste Cooking Oil over Typical Heterogeneous Base or Acid Catalysts," Catalysts, vol. 13, no. 3, Mar. 2023, Art. no. 546.
A. Ahmed, A. Ali, M. Mubashir, H. R. Lim, K. S. Khoo, and P. L. Show, "Process optimization and simulation of biodiesel synthesis from waste cooking oil through supercritical transesterification reaction without catalyst," Journal of Physics: Energy, vol. 5, no. 2, Feb. 2023, Art. no. 024003.
M. Hu, J. Pu, E. W. Qian, and H. Wang, "Biodiesel Production Using MgO–CaO Catalysts via Transesterification of Soybean Oil: Effect of MgO Addition and Insights of Catalyst Deactivation," BioEnergy Research, vol. 16, no. 4, pp. 2398–2410, Dec. 2023.
F. Guo, L. Wang, Y. Cao, P. He, and H. Li, "Efficient synthesis of ethylene carbonate via transesterification of ethylene glycol with dimethyl carbonate over Mg3Al1−xCexO composite oxide," Applied Catalysis A: General, vol. 662, Jul. 2023, Art. no. 119273.
P. A. Gangotena, S. Ponce, Á. Gallo-Córdova, D. A. Streitwieser, and J. R. Mora, "Highly Active MgP Catalyst for Biodiesel Production and Polyethylene Terephthalate Depolymerization," ChemistrySelect, vol. 7, no. 15, 2022, Art. no. e202103765.
A. Abdelhafiz et al., "Pulsed Light Synthesis of High Entropy Nanocatalysts with Enhanced Catalytic Activity and Prolonged Stability for Oxygen Evolution Reaction," Advanced Science, vol. 10, no. 18, 2023, Art. no. 2300426.
J. Liu et al., "Excess soluble alkalis to prepare highly efficient MgO with relative low surface oxygen content applied in DMC synthesis," Scientific Reports, vol. 11, no. 1, Oct. 2021, Art. no. 20931.
S. Xia et al., "Sustainable biodiesel production via transesterification of vegetable oils and waste frying oil over reusable magnetic Ca2Fe2O5/CaO@MgFe2O4-Fe2O3 catalyst," Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. 45, no. 3, pp. 8047–8061, Aug. 2023.
Y. Xie et al., "CaO-MgFe2O4@K2CO3 as a novel and retrievable nanocatalyst for two-step transesterification of used frying oils to biodiesel," Process Safety and Environmental Protection, vol. 172, pp. 195–210, Apr. 2023.
U. N. Khan et al., "Green synthesis of magnesium oxide nanosheets by using Citrullus colocynthis fruit extract and its use in biofuel production," Biomass and Bioenergy, vol. 167, Art. no. 106640, Dec. 2022.
N. Balaba et al., "Polysaccharides as Green Fuels for the Synthesis of MgO: Characterization and Evaluation of Antimicrobial Activities," Molecules, vol. 28, no. 1, Jan. 2023, Art. no. 142.
M. Ramezani Farani, M. Farsadrooh, I. Zare, A. Gholami, and O. Akhavan, "Green Synthesis of Magnesium Oxide Nanoparticles and Nanocomposites for Photocatalytic Antimicrobial, Antibiofilm and Antifungal Applications," Catalysts, vol. 13, no. 4, Apr. 2023, Art. no. 642.
I. Y. Dharmegowda, L. M. Muniyappa, P. Siddalingaiah, A. B. Suresh, M. P. Gowdru Chandrashekarappa, and C. Prakash, "MgO Nano-Catalyzed Biodiesel Production from Waste Coconut Oil and Fish Oil Using Response Surface Methodology and Grasshopper Optimization," Sustainability, vol. 14, no. 18, Jan. 2022, Art. no. 11132.
M. Cerón Ferrusca, R. Romero, S. L. Martínez, A. Ramírez-Serrano, and R. Natividad, "Biodiesel Production from Waste Cooking Oil: A Perspective on Catalytic Processes," Processes, vol. 11, no. 7, Jul. 2023, Art. no. 1952.
N. C. Joshi, P. Gururani, P. Bhatnagar, V. Kumar, and M. S. Vlaskin, "Advances in Metal Oxide-based Nanocatalysts for Biodiesel Production: A Review," ChemBioEng Reviews, vol. 10, no. 3, pp. 258–271, 2023.
A. A. Khaskheli, H. J. Arain, I. A. Memon, U. A. Rajput, and M. J. Ahsan, "Emission and Noise Characteristics of a Diesel Engine Fuelled with Diesel-Chicken Oil Biodiesel Blends," Engineering, Technology & Applied Science Research, vol. 10, no. 2, pp. 5387–5391, Apr. 2020.
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