Numerical and Experimental Investigation of Performance and Flooding Phenomena of a PEM Fuel Cell with and without Micro-Porous Layers
Received: 2 February 2024 | Revised: 13 February 2024 | Accepted: 21 February 2024 | Online: 29 February 2024
Corresponding author: Vu Duong
Abstract
This work presents the results of manufacturing a single Proton Exchange Membrane Fuel Cell (PEMFC) with Micro-Porous Layers (MPLs) and an active area of 25 cm2, and the experimental study required to build its polarization curve. Based on the physical model data, a numerical model of this PEMFC is created in the ANSYS PEM Fuel Cell module. Numerical simulations were performed with boundary conditions consistent with the experimental conditions on the test station. The calculation and experimental result comparison of the polarization curves for voltages ranging from 0.29 V to 0.94 V proved that the utilized numerical model is highly reliable. The simulation of PEMFC without MPLs was conducted according to other stable input parameters and boundary conditions. The results show that the PEMFC performance decreases significantly due to the flooding phenomenon inside PEMFC without MPLs compared to PEMFC with MPLs. Such phenomena are challenging to observe experimentally. Numerical modeling can be further used to optimize the fuel cell components.
Keywords:
fuel cell, micro-porous layer, current, flooding phenomenon, water contentDownloads
References
"COP28 Agreement Signals ‘Beginning of the End’ of the Fossil Fuel Era," UNFCCC. https://unfccc.int/news/cop28-agreement-signals-beginning-of-the-end-of-the-fossil-fuel-era?gad_source=1&gclid=Cj0KCQiAxOauBhCaARIsAEbUSQRWASTPzA5aFB6zP-sEO_gwJE2Kg-3YAaLVnNk4Hynw2ugUT4TyIYgaAlcgEALw_wcB.
M. Marappan et al., "Performance Studies of Proton Exchange Membrane Fuel Cells with Different Flow Field Designs – Review," The Chemical Record, vol. 21, no. 4, pp. 663–714, 2021.
C. Spiegel, Designing and Building Fuel Cells. New York, NY, USA: McGraw Hill, 2007.
A. Khadhraoui, T. Selmi, and A. Cherif, "Energy Management of a Hybrid Electric Vehicle," Engineering, Technology & Applied Science Research, vol. 12, no. 4, pp. 8916–8921, Aug. 2022.
S. N. M., O. Tremblay, and L.-A. Dessaint, "A generic fuel cell model for the simulation of fuel cell vehicles," in IEEE Vehicle Power and Propulsion Conference, Dearborn, MI, USA, Sep. 2009, pp. 1722–1729.
S. N. Motapon, O. Tremblay, and L.-A. Dessaint, "Development of a generic fuel cell model: application to a fuel cell vehicle simulation," International Journal of Power Electronics, vol. 4, no. 6, pp. 505–522, Jan. 2012.
C. Spiegel, PEM Fuel Cell Modeling and Simulation Using MATLAB. London, UK: Academic Press, 2008.
S. Javadpoor and D. Nazarpour, "Modeling a PV-FC-Hydrogen Hybrid Power Generation System," Engineering, Technology & Applied Science Research, vol. 7, no. 2, pp. 1455–1459, Apr. 2017.
J. Chakravorty, J. Saraswat, and V. Bhatia, "Modeling a Distributed Power Flow Controller with a PEM Fuel Cell for Power Quality Improvement," Engineering, Technology & Applied Science Research, vol. 8, no. 1, pp. 2585–2589, Feb. 2018.
S. Barhate, R. Mudhalwadkar, and S. Madhe, "Fault Detection Methods Suitable for Automotive Applications in Proton Exchange Fuel Cells," Engineering, Technology & Applied Science Research, vol. 12, no. 6, pp. 9607–9613, Dec. 2022.
M. A. Biberci and M. B. Celik, "Dynamic Modeling and Simulation of a PEM Fuel Cell (PEMFC) during an Automotive Vehicle’s Driving Cycle," Engineering, Technology & Applied Science Research, vol. 10, no. 3, pp. 5796–5802, Jun. 2020.
H. Bouzidi, L. Otmani, R. Doufnoune, L. Zerroual, and D. Benachour, "Influence of Membrane Type on Some Electrical Properties of a Single Microbial Fuel Cell," Engineering, Technology & Applied Science Research, vol. 12, no. 3, pp. 8492–8499, Jun. 2022.
G. Sasikumar, J. W. Ihm, and H. Ryu, "Dependence of optimum Nafion content in catalyst layer on platinum loading," Journal of Power Sources, vol. 132, no. 1, pp. 11–17, May 2004.
C.-J. Tseng and S.-K. Lo, "Effects of microstructure characteristics of gas diffusion layer and microporous layer on the performance of PEMFC," Energy Conversion and Management, vol. 51, no. 4, pp. 677–684, Apr. 2010.
N. Khajeh-Hosseini-Dalasm, M. J. Kermani, D. G. Moghaddam, and J. M. Stockie, "A parametric study of cathode catalyst layer structural parameters on the performance of a PEM fuel cell," International Journal of Hydrogen Energy, vol. 35, no. 6, pp. 2417–2427, Mar. 2010.
N. H. Hiep, N. Q. Quan, G. H. Thai, and P. T. San, "Numerical Modeling and Experimental Validation of a Hydrogen/Oxygen Fuel Cell for Underwater Vehicle Applications," SAE International, Warrendale, PA, USA, SAE Technical Paper 2023-01–5053, Aug. 2023.
A. Pfrang, S. Didas, and G. Tsotridis, "X-ray computed tomography of gas diffusion layers of PEM fuel cells: Segmentation of the microporous layer," Journal of Power Sources, vol. 235, pp. 81–86, Aug. 2013.
F. Aldakheel et al., "Gas permeability, wettability and morphology of gas diffusion layers before and after performing a realistic ex-situ compression test," Renewable Energy, vol. 151, pp. 1082–1091, May 2020.
ANSYS FLUENT Theory Guide 17.2. Canonsburg, PA, USA: ANSYS, 2022.
M. Arif, S. C. P. Cheung, and J. Andrews, "A systematic approach for matching simulated and experimental polarization curves for a PEM fuel cell," International Journal of Hydrogen Energy, vol. 45, no. 3, pp. 2206–2223, Jan. 2020.
I. Nitta, S. Karvonen, O. Himanen, and M. Mikkola, "Modelling the Effect of Inhomogeneous Compression of GDL on Local Transport Phenomena in a PEM Fuel Cell," Fuel Cells, vol. 8, no. 6, pp. 410–421, 2008.
M. Arif, S. C. P. Cheung, and J. Andrews, "Numerical investigation of effects of different flow channel configurations on the 100 cm2 PEM fuel cell performance under different operating conditions," Catalysis Today, vol. 397–399, pp. 449–462, Aug. 2022.
M. Arif, S. C. P. Cheung, and J. Andrews, "Influence of Hydrophobicity and Porosity of the Gas Diffusion Layer on Mass Transport Losses in PEM Fuel Cells: A Simulation Study Supported by Experiments," Energy & Fuels, vol. 34, no. 10, pp. 13010–13022, Oct. 2020.
W. Xiaofei, Q. Yang, Z. Zhigang, and X. Liusheng, "Investigation of Ship Vibration Effects on the Gas Distribution and Output Voltage of a Proton Exchange Membrane Fuel Cell," ACS Omega, vol. 7, no. 24, pp. 20569–20583, Jun. 2022.
J. Zhao, S. Shahgaldi, I. Alaefour, Q. Xu, and X. Li, "Gas permeability of catalyzed electrodes in polymer electrolyte membrane fuel cells," Applied Energy, vol. 209, pp. 203–210, Jan. 2018.
J. T. Gostick, M. W. Fowler, M. D. Pritzker, M. A. Ioannidis, and L. M. Behra, "In-plane and through-plane gas permeability of carbon fiber electrode backing layers," Journal of Power Sources, vol. 162, no. 1, pp. 228–238, Nov. 2006.
A. A. Shah, G.-S. Kim, P. C. Sui, and D. Harvey, "Transient non-isothermal model of a polymer electrolyte fuel cell," Journal of Power Sources, vol. 163, no. 2, pp. 793–806, Jan. 2007.
M. Secanell, K. Karan, A. Suleman, and N. Djilali, "Multi-variable optimization of PEMFC cathodes using an agglomerate model," Electrochimica Acta, vol. 52, no. 22, pp. 6318–6337, Jun. 2007.
G. Adilbish and Y.-T. Yu, "Effect of the Nafion content in the MPL on the catalytic activity of the Pt/C-Nafion electrode prepared by pulsed electrophoresis deposition," International Journal of Hydrogen Energy, vol. 42, no. 2, pp. 1181–1188, Jan. 2017.
S. Li, J. Yuan, M. Andersson, G. Xie, and B. Sundén, "Influence of anisotropic gas diffusion layers on transport phenomena in a proton exchange membrane fuel cell," International Journal of Energy Research, vol. 41, no. 14, pp. 2034–2050, 2017.
S. Li, J. Yuan, G. Xie, and B. Sundén, "Effects of agglomerate model parameters on transport characterization and performance of PEM fuel cells," International Journal of Hydrogen Energy, vol. 43, no. 17, pp. 8451–8463, Apr. 2018.
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