A Comparative Study of the Oxidation Behavior of Hot-Rolled Steel established from Medium and Thin Slabs oxidized in 20% H2O-N2 at 600-900°C
Received: 5 July 2023 | Revised: 27 November 2023 | Accepted: 29 November 2023 | Online: 8 February 2024
Corresponding author: Thanasak Nilsonthi
Abstract
This study focuses on the oxidation behavior of oxide scale on hot-rolled steel from a Thailand steel industry. Hot-rolled steel established from the medium and thin slabs was studied. The oxidation behavior was conducted in a horizontal furnace with 20%H2O-N2 to simulate steel oxidation during the hot rolling line. The scale was formed at a temperature range of 600-900°C for 30, 60, and 90 min. The scale morphology can be seen via Scanning Electron Microscope (SEM-EDS). The oxide phase was investigated via X-Ray Diffraction (XRD). The results show that iron oxides such as hematite (Fe2O3) and magnetite (Fe3O4) were produced on the studied steel. The oxidation behavior of the studied steel was followed by a parabolic law. The mass gain increased with increasing temperatures. The steel established from a medium slab exhibited a lower oxidation rate than the steel established from a thin slab. The reason for this could be the high amount of oxide containing silicon at the steel-scale interface, which promoted the oxidation resistance of the steel established from the medium slab. The influence of different slab types and its alloying elements was studied to comprehend the oxidation behavior. As a result, the alloying element in the hot-rolled steel was controlled in the design process.
Keywords:
water vapor, hot-rolled steel, medium slab, thin slab, oxidationDownloads
References
A. Ghosh and A. Chatterjee, Iron Making and Steelmaking: Theory and Practice. New Delhi, India: PHI Learning, 2008.
V. B. Ginzburg, Flat-Rolled Steel Processes: Advanced Technologies. New York, NY, USA: CRC Press, 2009.
R. Y. Chen and W. Y. D. Yeun, "Review of the High-Temperature Oxidation of Iron and Carbon Steels in Air or Oxygen," Oxidation of Metals, vol. 59, no. 5, pp. 433–468, Jun. 2003.
K. Ngamkham, N. Klubvihok, J. Tungtrongpairoj, and S. Chandra-Ambhorn, "Relationship between entry temperature and properties of thermal oxide scale on low carbon steel strips," in 14th International Conference on Metal forming, Krakow, Poland, Sep. 2012, pp. 991–994.
S. Chandra-ambhorn, K. Ngamkham, and N. Jiratthanakul, "Effects of Process Parameters on Mechanical Adhesion of Thermal Oxide Scales on Hot-Rolled Low Carbon Steels," Oxidation of Metals, vol. 80, no. 1, pp. 61–72, Aug. 2013.
R. Y. Chen and W. Y. D. Yuen, "Oxide-Scale Structures Formed on Commercial Hot-Rolled Steel Strip and Their Formation Mechanisms," Oxidation of Metals, vol. 56, no. 1, pp. 89–118, Aug. 2001.
L. Suarez, R. H. Petrov, L. A. I. Kestens, M. Lamberigts, and Y. Houbaert, "Texture Evolution of Tertiary Oxide Scale during Steel Plate Finishing Hot Rolling Simulation Tests," Materials Science Forum, vol. 550, pp. 557–562, 2007.
P. Sarrazin, A. Galerie, and J. Fouletier, Mechanisms of High Temperature Corrosion. Zurich, Switzerland: Trans Tech Publications, 2008.
T. Nilsonthi, J. Tungtrongpairoj, S. Chandra-Ambhorn, Y. Wouters, and A. Galerie, "Effect of silicon on formation and mechanical adhesion of thermal oxide scale grown on low carbon steels in a hot-rolling line," in 14th International Conference on Metal forming, Krakow, Poland, Sep. 2012, pp. 987–990.
T. Nilsonthi, S. Chandra-ambhorn, Y. Wouters, and A. Galerie, "Adhesion of Thermal Oxide Scales on Hot-Rolled Conventional and Recycled Steels," Oxidation of Metals, vol. 79, no. 3, pp. 325–335, Apr. 2013.
S. Chandra-ambhorn, T. Nilsonthi, Y. Wouters, and A. Galerie, "Oxidation of simulated recycled steels with 0.23 and 1.03wt.% Si in Ar–20%H2O at 900°C," Corrosion Science, vol. 87, pp. 101–110, Oct. 2014.
M. I. Mohamed, "Studies of the Properties and Microstructure of Heat Treated 0.27% C and 0.84% Mn Steel," Engineering, Technology & Applied Science Research, vol. 8, no. 5, pp. 3484–3487, Oct. 2018.
K. Touileb, A. Hedhibi, R. Djoudjou, A. Ouis, and M. L. Bouazizi, "Mixing Design for ATIG Morphology and Microstructure Study of 316L Stainless Steel," Engineering, Technology & Applied Science Research, vol. 9, no. 2, pp. 3990–3997, Apr. 2019.
I. H. Kara, T. A. I. Yousef, H. Ahlatci, and Y. Turen, "Ca and Ce Effect on the Corrosion Resistance of Hot-Rolled AZ31 Mg Alloys," Engineering, Technology & Applied Science Research, vol. 10, no. 1, pp. 5113–5116, Feb. 2020.
W. Wongpromrat, H. Thaikan, W. Chandra-ambhorn, and S. Chandra-ambhorn, "Chromium Vaporisation from AISI 441 Stainless Steel Oxidised in Humidified Oxygen," Oxidation of Metals, vol. 79, no. 5, pp. 529–540, Jun. 2013.
P. Promdirek, G. Lothongkum, S. Chandra-Ambhorn, Y. Wouters, and A. Galerie, "Oxidation Kinetics of AISI 441 Ferritic Stainless Steel at High Temperatures in CO2 Atmosphere," Oxidation of Metals, vol. 81, no. 3, pp. 315–329, Apr. 2014.
W. Wongpromrat et al., "Possible connection between nodule development and presence of niobium and/or titanium during short time thermal oxidation of AISI 441 stainless steel in wet atmosphere," Materials at High Temperatures, vol. 32, no. 1–2, pp. 22–27, Jan. 2015.
A. Atkinson, "Transport processes during the growth of oxide films at elevated temperature," Reviews of Modern Physics, vol. 57, no. 2, pp. 437–470, Apr. 1985.
D. Landolt, Corrosion et chimie de surfaces des metaux, Reimp. corr. Lausanne, Switzerland: PPUR Press, 1997.
P. Kofstad, High temperature corrosion. London, UK: Elsevier, 1988.
M. J. L. Gines, G. J. Benitez, T. Perez, E. Merli, M. A. Firpo, and W. EgliI, "Study of the picklability of 1.8 mm hot-rolled steel strip in hydrochloric acid," Latin American applied research, vol. 32, no. 4, pp. 281–288, Dec. 2002.
Z. Y. Jiang, A. K. Tieu, W. H. Sun, J. N. Tang, and D. B. Wei, "Characterisation of thin oxide scale and its surface roughness in hot metal rolling," Materials Science and Engineering: A, vol. 435–436, pp. 434–438, Nov. 2006.
M. Zhang and G. Shao, "Characterization and properties of oxide scales on hot-rolled strips," Materials Science and Engineering: A, vol. 452–453, pp. 189–193, Apr. 2007.
Y.-L. Yang, C.-H. Yang, S.-N. Lin, C.-H. Chen, and W.-T. Tsai, "Effects of Si and its content on the scale formation on hot-rolled steel strips," Materials Chemistry and Physics, vol. 112, no. 2, pp. 566–571, Dec. 2008.
A. Segawa, "Reproduction and Deformation Characteristics of Oxide Scale in Hot Rolling Using Vacuum Rolling Mill," Materials Science Forum, vol. 696, pp. 150–155, 2011.
S. Taniguchi, K. Yamamoto, D. Megumi, and T. Shibata, "Characteristics of scale/substrate interface area of Si-containing low-carbon steels at high temperatures," Materials Science and Engineering: A, vol. 308, no. 1, pp. 250–257, Jun. 2001.
T. Ishitsuka, Y. Inoue, and H. Ogawa, "Effect of Silicon on the Steam Oxidation Resistance of a 9%Cr Heat Resistant Steel," Oxidation of Metals, vol. 61, no. 1, pp. 125–142, Feb. 2004.
M. Takeda and T. Onishi, "Oxidation Behavior and Scale Properties on the Si Containing Steels," Materials Science Forum, vol. 522–523, pp. 477–488, 2006.
T. Nishimoto, K. Honda, Y. Kondo, and K. Uemura, "Effects of Si Content on the Oxidation Behavior of Fe–Si Alloys in Air," Materials Science Forum, vol. 696, pp. 126–131, 2011.
E. Ahtoy, "Effect of alloying elements (Si, P, Al, B) on low carbon steel oxidation in process at high temperatures mechanisms and modelling," Ph.D. dissertation, Grenoble INPG, Grenoble, France, 2010.
R. Y. Chen and W. Y. D. Yuen, "Effects of the Presence of Water Vapour on the Oxidation Behaviour of Low Carbon–Low Silicon Steel in 1 %O2–N2 at 1073 K," Oxidation of Metals, vol. 79, no. 5, pp. 655–678, Jun. 2013.
R. Y. Chen and W. Y. D. Yuen, "Effects of the Presence of Water Vapour on the Oxidation Behaviour of Low Carbon–Low Silicon Steel in 1 %O2–N2 at 1,173 and 1,273 K," Oxidation of Metals, vol. 79, no. 5, pp. 679–699, Jun. 2013.
R. Y. Chen and W. Y. D. Yuen, "Longer Term Oxidation Kinetics of Low Carbon, Low Silicon Steel in 17H2O–N2 at 900°C," Oxidation of Metals, vol. 85, no. 5, pp. 489–507, Jun. 2016.
D. R. Gaskell, Introduction to metallurgical thermodynamics, 2nd ed. New York, NY, USA: McGraw-Hill, 1981.
R. Y. Chen and W. Y. D. Yuen, "Oxidation of Low-Carbon Steel in 17H2O-N2 at 900 °C," Metallurgical and Materials Transactions A, vol. 40, no. 13, pp. 3091–3107, Dec. 2009.
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