A Technological Nanofluid for Washing Off Oil Deposits and Increasing Oil Recovery

Authors

  • Nora Mamulaishvili Technical Faculty, Batumi Shota Rustaveli State University, Georgia
  • Gaioz Partskhaladze Technical Faculty, Batumi Shota Rustaveli State University, Georgia
  • Gocha Chavleshvili Technical Faculty, Batumi Shota Rustaveli State University, Georgia
  • Tea Khitarishvili Georgian Technical University, Georgia | Department of Petroleum Chemistry, Oil Academy of Azerbaijan, Azerbaijan
  • Nigar Salimova Department of Petroleum Chemistry, Oil Academy of Azerbaijan, Azerbaijan
Volume: 13 | Issue: 4 | Pages: 11058-11063 | August 2023 | https://doi.org/10.48084/etasr.5904

Abstract

The productivity of wells in the late stage of oil production is directly related to oil deposits, which gradually form blockages, fill the pipeline, and interfere with the free movement of the flow of produced oil. Based on chemical composition, oil deposits are difficult to remove and require the selection of process fluids. An extractive method is proposed for the removal of oil deposits with the participation of process fluids, including nanofluids. The proposed nanofluid was prepared on the basis of low-viscosity petroleum oil with the addition of an organic solvent, a mixture of various classes of surface-active substances (surfactants), and alkali metal salts. The nanofluid contains a nanosolution based on alkali metal salts, with concentrations of Na3PO4=13700ppm, KCl=950ppm, and CaCl2=241ppm, which were determined by the readings of an ICPE-9820 spectrometer. It was found that the tested process fluid reduces the viscosity of deposits and interfacial tension and leads to an increase in fluid movement in the pipeline. The experiments were carried out in the direction of reducing the interfacial tension at the interface with the solvent. It was shown that the process of sediment reduction depends on the composition of the ARPD, the surfactant, the composition of the solvent, and the salinity of the nanosolution. It is advisable to flush oil deposits from the surface of the tubing using the process fluid when creating a circular circulation in a closed annular space - tubing – annulus circuit.

Keywords:

oil deposits, solvent, surface tension, surfactant, tubing

Downloads

Download data is not yet available.

References

D. Zareei, D. Luo, K. Kostarelos, and Z. Ren, "Sodium nanofluid for efficient oil recovery in heavy oil and oil sand reservoirs,"Soft Science, vol. 1, no. 2, Sep. 2021.

J. Kever, "Inexpensive, Non-Toxic Nanofluid Could Be a Game-Changer for Oil Recovery,"University of Houston, Sep. 10, 2020. https://uh.edu/news-events/stories/2020/september-2020/09102020ren-nanofluid-oil.php.

G. Kumar, U. S. Behera, E. Mani, and J. S. Sangwai, "Engineering the Wettability Alteration of Sandstone Using Surfactant-Assisted Functional Silica Nanofluids in Low-Salinity Seawater for Enhanced Oil Recovery,"ACS Engineering Au, vol. 2, no. 5, pp. 421–435, Oct. 2022.

I. Nowrouzi, A. Khaksar Manshad, and A. H. Mohammadi, "Effects of MgO, γ-Al2O3, and TiO2 Nanoparticles at Low Concentrations on Interfacial Tension (IFT), Rock Wettability, and Oil Recovery by Spontaneous Imbibition in the Process of Smart Nanofluid Injection into Carbonate Reservoirs,"ACS Omega, vol. 7, no. 26, pp. 22161–22172, Jul. 2022.

K. Fujita et al., "Evaluation of Asphaltene Adsorption Free Energy at the Oil–Water Interface: Effect of Oil Solvents,"Energy & Fuels, vol. 36, no. 3, pp. 1338–1349, Feb. 2022.

S. M. Alsaedy and N. Aljalawi, "The Effect of Nanomaterials on the Properties of Limestone Dust Green Concrete,"Engineering, Technology & Applied Science Research, vol. 11, no. 5, pp. 7619–7623, Oct. 2021.

H. B. Lanjwani, M. S. Chandio, K. Malik, and M. M. Shaikh, "Stability Analysis of Boundary Layer Flow and Heat Transfer of Fe2O3 and Fe-Water Base Nanofluid οver a Stretching/Shrinking Sheet with Radiation Effect,"Engineering, Technology & Applied Science Research, vol. 12, no. 1, pp. 8114–8122, Feb. 2022.

A. S. Parfenov, Y. A. Senatov, P. A. Rodinova, and A. A. Tuvin, "Application of Lubricants of Plant Origin Modified with Carbon Nanoparticles Under Abrasive Friction,"Современные наукоемкие технологии. Региональное приложение, vol. 4, no. 68, pp. 63–68, 2021.

S. G. Aydin and A. Ozgen, "Bio-Based Jet Fuel Production by Transesterification of Nettle Seeds,"Engineering, Technology & Applied Science Research, vol. 13, no. 1, pp. 10116–10120, Feb. 2023.

M. A. Silin et al., "Aspects of Interaction of Surfactant—Acid Compositions at Phase Boundary with Hydrocarbons,"Russian Journal of Applied Chemistry, vol. 92, no. 12, pp. 1810–1819, Dec. 2019.

J. Fink, Petroleum Engineer’s Guide to Oil Field Chemicals and Fluids, 2nd ed. Amsterdam , Netherlands: Elsevier, 2015.

М. Б. Турукалов, "Критерии выбора эффективных углеводородных растворителей для удаления асфальто-смоло-парафиновых отложений," Ph.D. dissertation, Kuban State Technological University, 2007.

S. Tanirbergenova, Y. Ongarbayev, Y. Tileuberdi, A. Zhambolova, E. Kanzharkan, and Z. Mansurov, "Selection of Solvents for the Removal of Asphaltene–Resin–Paraffin Deposits,"Processes, vol. 10, no. 7, Jul. 2022, Art. no. 1262.

L. V. Ivanova and V. N. Koshelev, "Removal of asphalt-resin-paraffin deposits of different nature. Electronic scientific journal," Electronic scientific journal Oil and Gas Business, vol. 2, pp. 257–268, 2011.

"Solvents 646 and 647 - Specifications."https://www.dcpt.ru/blog/rastvoriteli-646-647-tekhnicheskie-kharakteristiki/.

N. Mamulaishvili, T. Mamedova, and T. Hitarishvili, "Concretion of Asfaltic –Resineus Compounds Off the Worked-Out Motor Oil with Use of Chemical Reagents,"GISAP: Physics, Mathematics and Chemistry, no. 3, 2014.

N. Mamulaishvili, G. Partskhaladze, G. Chavleshvili, O. Janelidze, and N. Salimova, "Research results on the effects of magnetic fields on crude oil,"Global Journal of Engineering and Technology Advances, vol. 5, no. 3, pp. 50–58, 2020.

N. Mamulaishvili, G. Partskhaladze, G. Chavleshvili, O. Janelidze, and D. Chxaidze, "Thermolysis of petroleum oil and solubility of deposits,"Global Journal of Engineering and Technology Advances, vol. 13, no. 3, pp. 086–095, 2022.

М. В. Santyurova and N. A. Demyanova, "ARDP removal from the walls of small-diameter oil pipelines," in VIII Всероссийскаяконференция «Молодёжьинаука», Секция «Нефтьигаз», 2012, [Online]. Available: https://elib.sfu-kras.ru/handle/2311/7045.

V. A. Volkov, V. G. Belikova, and A. N. Turapin, "Formulation for Removing Asphaltene-Tar-Paraffin Deposits and Hydrophobization of Formation Bottom Zone," RU2307860C2, Oct. 10, 2007.

M. Dierker and H. J. Schäfer, "Surfactants from oleic, erucic and petroselinic acid: Synthesis and properties,"European Journal of Lipid Science and Technology, vol. 112, no. 1, pp. 122–136, 2010.

"Simultaneous ICP Atomic Emission Spectrometers ICPE-9800 Series,"Shimadzu. https://www.shimadzu.com/an/products/elemental-analysis/inductively-coupled-plasma-emission-spectroscopy/icpe-9800-series/index.html.

"Supply BIOBASE BK-RZT BK-R2S Abbe Digital Honey Refractometer Honey Wholesale Factory,"BIOBASE GROUP. https://www.biobase.com/product/biobase-bk-rzt-bk-r2s-abbe-digital-honey-refractometer-honey.

Downloads

How to Cite

[1]
N. Mamulaishvili, G. Partskhaladze, G. Chavleshvili, T. Khitarishvili, and N. Salimova, “A Technological Nanofluid for Washing Off Oil Deposits and Increasing Oil Recovery”, Eng. Technol. Appl. Sci. Res., vol. 13, no. 4, pp. 11058–11063, Aug. 2023.

Metrics

Abstract Views: 819
PDF Downloads: 663

Metrics Information