Hydrogeochemical Assessment of Groundwater Quality and Suitability for Drinking and Agricultural Use. The Case Study of Fars Province, Iran

Authors

  • Yasamin Aghaei Faculty of Civil Engineering, Iran University of Science and Technology, Iran
  • Mohammad Nazari-Sharabian Department of Mathematics, Engineering, and Computer Science, West Virginia State University, USA https://orcid.org/0000-0002-0568-4603
  • Hossein Afzalimehr Faculty of Civil Engineering, Iran University of Science and Technology, Iran
  • Moses Karakouzian Department of Civil and Environmental Engineering and Construction, University of Nevada, Las Vegas, USA
Volume: 13 | Issue: 3 | Pages: 10797-10807 | June 2023 | https://doi.org/10.48084/etasr.5884

Abstract

This study aims to evaluate the hydrogeochemistry of aquifers in Fars province, Iran, from 2007 to 2017 and assess the groundwater’s suitability for drinking and agricultural uses. A total of 35,000 samples were collected from wells and qanats across the province. Piper, Gibbs, and Durov diagrams were used to assess the hydrochemical facies and processes. Cross plots of different ions were investigated to assess ion exchange and determine the effects of anthropogenic activities, as well as the weathering and dissolution of different rocks and minerals in the aquifers. Groundwater quality and suitability for agricultural and drinking purposes were also assessed using physicochemical parameters including pH, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Total Hardness (TH), and calcium, magnesium, sodium, potassium, bicarbonate, sulfate, and chloride concentrations. Suitability for domestic purposes was assessed by comparing these values with the WHO standards. Sodium and alkalinity hazards, including Sodium Adsorption Ratio (SAR), sodium percentage (Na%), Permeability Index (PI), Magnesium Hazard (MH), and Residual Sodium Carbonate (RSC) were used to assess irrigation suitability, along with plotting Wilcox and USSL diagrams.

Keywords:

groundwater chemistry, hydrochemical facies, suitability analysis, Geographic Information System (GIS)

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References

B. Tlili-Zrelli, F. Hamzaoui-Azaza, M. Gueddari, and R. Bouhlila, "Geochemistry and quality assessment of groundwater using graphical and multivariate statistical methods. A case study: Grombalia phreatic aquifer (Northeastern Tunisia)," Arabian Journal of Geosciences, vol. 6, no. 9, pp. 3545–3561, Sep. 2013. DOI: https://doi.org/10.1007/s12517-012-0617-3

P. Doll, H. Muller Schmied, C. Schuh, F. T. Portmann, and A. Eicker, "Global-scale assessment of groundwater depletion and related groundwater abstractions: Combining hydrological modeling with information from well observations and GRACE satellites," Water Resources Research, vol. 50, no. 7, pp. 5698–5720, 2014. DOI: https://doi.org/10.1002/2014WR015595

M. Taheriyoun, H. Marzban, M. Geranmehr, and M. Nazari-Sharabian, "Optimization of Pollutant Discharge Permits, Using the Trading Ratio System: A Case Study," Earth, vol. 3, no. 3, pp. 814–824, Sep. 2022. DOI: https://doi.org/10.3390/earth3030046

M. Maghrebi et al., "Iran’s Groundwater Hydrochemistry," Earth and Space Science, vol. 8, no. 8, 2021, Art. no. e2021EA001793. DOI: https://doi.org/10.1029/2021EA001793

M. N. Sharabian, S. Ahmad, and M. Karakouzian, "Climate Change and Eutrophication: A Short Review," Engineering, Technology & Applied Science Research, vol. 8, no. 6, pp. 3668–3672, Dec. 2018. DOI: https://doi.org/10.48084/etasr.2392

A. N. Laghari, Z. A. Siyal, D. K. Bangwar, M. A. Soomro, G. D. Walasai, and F. A. Shaikh, "Groundwater Quality Analysis for Human Consumption: A Case Study of Sukkur City, Pakistan," Engineering, Technology & Applied Science Research, vol. 8, no. 1, pp. 2616–2620, Feb. 2018. DOI: https://doi.org/10.48084/etasr.1768

Y. Kassem, H. Gokcekus, and T. Rizza, "Groundwater Quality Assessment Based on Water Quality Index in Northern Cyprus," Engineering, Technology & Applied Science Research, vol. 12, no. 2, pp. 8435–8443, Apr. 2022. DOI: https://doi.org/10.48084/etasr.4790

"An Analysis of Iran’s Water Crisis and Its Impacts," IPRC (Iranian Parliament Research Center), Iran, Report No. 15608, (in Persian), 2017.

S. Venkateswaran, M. V. Prabhu, M. M. Rafi, and K. L. K. Vallel, "Assessment of Groundwater Quality for Irrigational Use in Cumbum Valley, Madurai District, Tamilnadu, India," Nature Environment and Pollution Technology, vol. 10, no. 2, pp. 207–212, 2011.

A. Jafar Ahamed, S. Ananthakrishnan, K. Loganathan, and K. Manikandan, "Assessment of groundwater quality for irrigation use in Alathur Block, Perambalur District, Tamilnadu, South India," Applied Water Science, vol. 3, no. 4, pp. 763–771, Dec. 2013. DOI: https://doi.org/10.1007/s13201-013-0124-z

K. Arumugam and K. Elangovan, "Hydrochemical characteristics and groundwater quality assessment in Tirupur Region, Coimbatore District, Tamil Nadu, India," Environmental Geology, vol. 58, no. 7, pp. 1509–1520, Oct. 2009. DOI: https://doi.org/10.1007/s00254-008-1652-y

R. Reghunath, T. R. S. Murthy, and B. R. Raghavan, "The utility of multivariate statistical techniques in hydrogeochemical studies: an example from Karnataka, India," Water Research, vol. 36, no. 10, pp. 2437–2442, May 2002. DOI: https://doi.org/10.1016/S0043-1354(01)00490-0

P. Singh, A. Malik, D. Mohan, and S. Sinha, "Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomti River (India)—a case study," Water Research, vol. 38, no. 18, pp. 3980–3992, Nov. 2004. DOI: https://doi.org/10.1016/j.watres.2004.06.011

E. Tziritis, K. Skordas, and A. Kelepertsis, "The use of hydrogeochemical analyses and multivariate statistics for the characterization of groundwater resources in a complex aquifer system. A case study in Amyros River basin, Thessaly, central Greece," Environmental Earth Sciences, vol. 75, no. 4, Feb. 2016, Art. no. 339. DOI: https://doi.org/10.1007/s12665-015-5204-y

N. Tavanpour and A. Asghar Ghaemi, "Zoning of Fars Province in Terms of Rain-fed Winter Wheat Cultivation Based on Precipitation and Morphological Factors," Iranian Journal of Irrigation & Drainage, vol. 10, no. 4, pp. 544–555, Oct. 2016.

WHO, Guidelines for Drinking-water Quality. Geneva, Switzerland: World Health Organization, 1993.

R. S. Laboratory (U.S.), Diagnosis and Improvement of Saline and Alkali Soils. Washington, DC, USA: U.S. Department of Agriculture, 1954.

L. V. Wilcox, Classification and Use of Irrigation Waters. Washington, DC, USA: U.S. Department of Agriculture, 1955.

Richards, L. A., "Diagnosis and Improvement of Saline and Alkali Soils,"Agric. Handbook, vol. 60, no. 160. US Dept. of Agriculture, 1955.

Szabolcs I., "The influence of irrigation water of high Sodium Carbonate content on soils," Agrokemia es talajtan, vol. 13, pp. 237–246, 1964.

A. M. Piper, "A graphic procedure in the geochemical interpretation of water-analyses," Eos, Transactions American Geophysical Union, vol. 25, no. 6, pp. 914–928, 1944. DOI: https://doi.org/10.1029/TR025i006p00914

S. A. Durov, "Natural waters and graphical representation of their composition: Doklady Akademii Nauk," Union of Sovietic Socialist Republics, vol. 59, pp. 87–90, 1948.

R. J. Gibbs, "Mechanisms Controlling World Water Chemistry," Science, vol. 170, no. 3962, pp. 1088–1090, Dec. 1970. DOI: https://doi.org/10.1126/science.170.3962.1088

"دفتر اطلاعات و داده های آب کشور," IRAN Water Resources Management Company. https://data.wrm.ir/.

APHA, Standard Methods for the Examination of Water and Wastewater. Washington, DC, USA: American Public Health Association, 1926.

P. A. Domenico, P. A. Domenico, and F. W. Schwartz, Physical and chemical hydrogeology. New York, NY, USA: Wiley, 1990.

"RockWare Geoscientific Software Consulting & Training." https://www.rockware.com/.

J. Gaillardet, B. Dupre, P. Louvat, and C. J. Allegre, "Global silicate weathering and CO2 consumption rates deduced from the chemistry of large rivers," Chemical Geology, vol. 159, no. 1, pp. 3–30, Jul. 1999. DOI: https://doi.org/10.1016/S0009-2541(99)00031-5

M. Meybeck, "Global chemical weathering of surficial rocks estimated from river dissolved loads," American Journal of Science, vol. 287, no. 5, pp. 401–428, May 1987. DOI: https://doi.org/10.2475/ajs.287.5.401

G. Han and C.-Q. Liu, "Water geochemistry controlled by carbonate dissolution: a study of the river waters draining karst-dominated terrain, Guizhou Province, China," Chemical Geology, vol. 204, no. 1, pp. 1–21, Mar. 2004. DOI: https://doi.org/10.1016/j.chemgeo.2003.09.009

A. E. Clark, J. S. Herman, and B. F. Jones, "The chemical influence of clay minerals on groundwater composition in a lithologically heterogeneous carbonate aquifer," in 7th International Symposium on Water-Rock Interaction, Park City, Utah, USA, Jul. 1992, pp. 779–782.

M. Jalali, "Geochemistry characterization of groundwater in an agricultural area of Razan, Hamadan, Iran," Environmental Geology, vol. 56, no. 7, pp. 1479–1488, Feb. 2009. DOI: https://doi.org/10.1007/s00254-008-1245-9

R. Blake, "The origin of high sodium bicarbonate waters in the Otway Basin, Victoria, Australia," in 6th International Symposium on Water-Rock Interaction, Rotterdam, Netherlands, Aug. 1989, pp. 83–85.

T. E. Cerling, B. L. Pederson, and K. L. Von Damm, "Sodium-calcium ion exchange in the weathering of shales: Implications for global weathering budgets," Geology, vol. 17, no. 6, pp. 552–554, Jun. 1989. DOI: https://doi.org/10.1130/0091-7613(1989)017<0552:SCIEIT>2.3.CO;2

M. D. Foster, "The origin of high sodium bicarbonate waters in the Atlantic and Gulf Coastal Plains," Geochimica et Cosmochimica Acta, vol. 1, no. 1, pp. 33–48, Jan. 1950. DOI: https://doi.org/10.1016/0016-7037(50)90007-X

H. Schoeller, "Qualitative Evaluation of Groundwater Resources," in Methods and Technics of Groundwater Investigation and Development, New York, NY, USA: United Nations, 1967, pp. 44–52.

P. Li, J. Wu, and H. Qian, "Assessment of groundwater quality for irrigation purposes and identification of hydrogeochemical evolution mechanisms in Pengyang County, China," Environmental Earth Sciences, vol. 69, no. 7, pp. 2211–2225, Aug. 2013. DOI: https://doi.org/10.1007/s12665-012-2049-5

S. Ahmad and R. Singh, "Spatial Distribution and Health Risk Assessment based on Groundwater Fluoride Enrichment in Gaya, Bihar, India," Engineering, Technology & Applied Science Research, vol. 13, no. 1, pp. 9825–9829, Feb. 2023. DOI: https://doi.org/10.48084/etasr.5397

S. Ahmad and R. Singh, "Groundwater Quality Assessment Based on a Statistical Approach in Gaya District, Bihar," Engineering, Technology & Applied Science Research, vol. 13, no. 1, pp. 9867–9871, Feb. 2023. DOI: https://doi.org/10.48084/etasr.5421

K. Neeti and R. Singh, "Groundwater Quality Assessment and Health Risks from Fluoride in Jamui, Bihar," Engineering, Technology & Applied Science Research, vol. 13, no. 1, pp. 10204–10208, Feb. 2023. DOI: https://doi.org/10.48084/etasr.5576

D. Carroll, Rain water as a chemical agent of geological processes: A review. New York, NY, USA: United States Government Publishing, 1962.

R. A. Freeze and J. A. Cherry, Groundwater. Hoboken, NJ, USA: Prentice-Hall, 1979.

Davies, S. N., & DeWiest, R. J. M., Hydrogeology, New York: Wiley, 1966.

C. N. Sawyer and P. L. McCarty, Chemistry for sanitary engineers. New York, NY, USA: McGraw-Hill, 1967.

K. R. Karanth, Ground water assessment, development, and management. New York, NY, USA: Tata McGraw-Hill Education, 1987.

M. Loizidou and E. G. Kapetanios, "Effect of leachate from landfills on underground water quality," Science of The Total Environment, vol. 128, no. 1, pp. 69–81, Jan. 1993. DOI: https://doi.org/10.1016/0048-9697(93)90180-E

A. Saleh, F. Al-Ruwaih, and M. Shehata, "Hydrogeochemical processes operating within the main aquifers of Kuwait," Journal of Arid Environments, vol. 42, no. 3, pp. 195–209, Jul. 1999. DOI: https://doi.org/10.1006/jare.1999.0511

W. P. Kelley, Alkali Soils: Their Formation, Properties, and Reclamation. Ann Arbor, MI, USA: University Microfilms, 1951.

D. K. Todd, Groundwater hydrology. New York, NY, USA: Wiley, 1980.

L. V. Wilcox, The quality of water for irrigation use. Washington DC, USA: US Department of Agriculture, 1948.

L. D. Doneen, "Salination of soil by salts in the irrigation water," Eos, Transactions American Geophysical Union, vol. 35, no. 6, pp. 943–950, 1954. DOI: https://doi.org/10.1029/TR035i006p00943

K. V. Paliwal, "Effect of gypsum application on the quality of irrigation waters," The Madras Agricultural Journal, vol. 59, pp. 646–647, 1967.

L. A. Richards, "Diagnosis and Improvement of Saline and Alkali Soils," Soil Science, vol. 78, no. 2, Aug. 1954, Art. no. 154. DOI: https://doi.org/10.1097/00010694-195408000-00012

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[1]
Aghaei , Y., Nazari-Sharabian, M., Afzalimehr, H. and Karakouzian, M. 2023. Hydrogeochemical Assessment of Groundwater Quality and Suitability for Drinking and Agricultural Use. The Case Study of Fars Province, Iran. Engineering, Technology & Applied Science Research. 13, 3 (Jun. 2023), 10797–10807. DOI:https://doi.org/10.48084/etasr.5884.

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