Bio-Based Jet Fuel Production by Transesterification of Nettle Seeds
Received: 12 December 2022 | Revised: 23 December 2022 | Accepted: 5 January 2023 | Online: 5 February 2023
Corresponding author: Sinem Gurkan Aydin
Abstract
The use of petroleum-based fuels in air transport and the increase in oil prices over the years have increased fuel costs. Due to this increase, fuel manufacturers and airline companies have started to search for alternative fuels. Since aviation has an important place in the transportation sector, biomass has the greatest potential in the search for renewable energy sources. Biological substances of plant and animal origin and containing carbon compounds are energy sources, and the fuels produced from them are called biofuels. Biofuels are an important source of sustainable energy, which greatly reduces the greenhouse gas effect, improves weather conditions, reduces dependence on oil produced from fossil fuels, and is important for new markets. The nettle seed oil used in the current study was purchased from the local market and was obtained using the cold-pressing method at low temperatures. After the completion of the transesterification process, a two-phase mixture consisting of biofuel-glycerin was obtained, and the upper phase containing fatty acids was taken and transferred to a clean tube. After the final washing processes, bio jet fuel was obtained by adding chemicals at certain rates. The analysis of the obtained fuel was conducted at the Tubitak Marmara Research Centre. When the report was evaluated and compared with international standards, consistent results were obtained. It can be predicted that sustainable fuels can replace fossil fuels in the future.
Keywords:
sustainable energy, bio-based jet fuel, transesterification, nettle seedsDownloads
References
"Jet Fuel Price Monitor," IATA. https://www.iata.org/en/publications/economics/fuel-monitor.
IEA, Key World Energy Statistics. Paris, France: International Energy Agency, 2016.
"Environmental Trends in Aviation to 2050," in ICAO Environmental Report, Aviation and Climate Change, ICAO, 2016, pp. 16–22.
Biofuels for Aviation: Technology Brief. IRENA, 2017.
IATA Economic Briefing: Airline Fuel and Labour Cost Share. IATA, 2010.
IATA 2015 Report on Alternative Fuels. IATA, 2015.
C. D. Klingshirn et al., "Hydroprocessed Renewable Jet Fuel Evaluation, Performance, and Emissions in a T63 Turbine Engine," Journal of Engineering for Gas Turbines and Power, vol. 134, no. 5, Mar. 2012, Art. no. 051506. DOI: https://doi.org/10.1115/1.4004841
T. Rahmes et al., "Sustainable Bio-Derived Synthetic Paraffinic Kerosene (Bio-SPK) Jet Fuel Flights and Engine Tests Program Results," in 9th AIAA Aviation Technology, Integration, and Operations Conference, Hilton Head, SC, USA, Sep. 2009. DOI: https://doi.org/10.2514/6.2009-7002
S. Blakey, L. Rye, and C. W. Wilson, "Aviation gas turbine alternative fuels: A review," Proceedings of the Combustion Institute, vol. 33, no. 2, pp. 2863–2885, Jan. 2011. DOI: https://doi.org/10.1016/j.proci.2010.09.011
R. L. Speth, C. Rojo, R. Malina, and S. R. H. Barrett, "Black carbon emissions reductions from combustion of alternative jet fuels," Atmospheric Environment, vol. 105, pp. 37–42, Mar. 2015. DOI: https://doi.org/10.1016/j.atmosenv.2015.01.040
M. Badami, P. Nuccio, D. Pastrone, and A. Signoretto, "Performance of a small-scale turbojet engine fed with traditional and alternative fuels," Energy Conversion and Management, vol. 82, pp. 219–228, Jun. 2014. DOI: https://doi.org/10.1016/j.enconman.2014.03.026
J. Li, G. Yang, Y. Yoneyama, T. Vitidsant, and N. Tsubaki, "Jet fuel synthesis via Fischer–Tropsch synthesis with varied 1-olefins as additives using Co/ZrO2–SiO2 bimodal catalyst," Fuel, vol. 171, pp. 159–166, May 2016. DOI: https://doi.org/10.1016/j.fuel.2015.12.062
T. Hanaoka, T. Miyazawa, K. Shimura, and S. Hirata, "Jet fuel synthesis in hydrocracking of Fischer–Tropsch product over Pt-loaded zeolite catalysts prepared using microemulsions," Fuel Processing Technology, vol. 129, pp. 139–146, Jan. 2015. DOI: https://doi.org/10.1016/j.fuproc.2014.09.011
T. Hanaoka, T. Miyazawa, K. Shimura, and S. Hirata, "Jet fuel synthesis from Fischer–Tropsch product under mild hydrocracking conditions using Pt-loaded catalysts," Chemical Engineering Journal, vol. 263, pp. 178–185, Mar. 2015. DOI: https://doi.org/10.1016/j.cej.2014.11.042
M. He, M. Wang, G. Tang, Y. Fang, and T. Tan, "From medium chain fatty alcohol to jet fuel: Rational integration of selective dehydration and hydro-processing," Applied Catalysis A: General, vol. 550, pp. 160–167, Jan. 2018. DOI: https://doi.org/10.1016/j.apcata.2017.11.009
G. Nie, X. Zhang, L. Pan, M. Wang, and J.-J. Zou, "One-pot production of branched decalins as high-density jet fuel from monocyclic alkanes and alcohols," Chemical Engineering Science, vol. 180, pp. 64–69, Apr. 2018. DOI: https://doi.org/10.1016/j.ces.2018.01.024
K. P. Brooks et al., "Chapter 6 - Low-Carbon Aviation Fuel Through the Alcohol to Jet Pathway," in Biofuels for Aviation, C. J. Chuck, Ed. New York, NY, USA: Academic Press, 2016, pp. 109–150. DOI: https://doi.org/10.1016/B978-0-12-804568-8.00006-8
"Technology Roadmap - Biofuels for Transport – Analysis," IEA. https://www.iea.org/reports/technology-roadmap-biofuels-for-transport.
M. Bernabei, R. Reda, R. Galiero, and G. Bocchinfuso, "Determination of total and polycyclic aromatic hydrocarbons in aviation jet fuel," Journal of Chromatography A, vol. 985, no. 1, pp. 197–203, Jan. 2003. DOI: https://doi.org/10.1016/S0021-9673(02)01826-5
A. Agosta, "Development of a chemical surrogate for JP-8 aviation fuel using a pressurized flow reactor," M.S. thesis, Drexel University, Philadelphia, PA, USA, 2002.
Aviation Fuels: Technical Review. San Ramon, CA, USA: Chevron, 2007.
J. Holmgren, "Biofuels: Unlocking the Potential," in The International Conference on Biorefinery, Syracuse, NY, USA, Oct. 2009, pp. 1–44.
ASTM D1655-20(2020), Standard Specification for Aviation Turbine Fuels. West Conshohocken, PA, USA: ASTM International, 2020.
K. K. Gupta, A. Rehman, and R. M. Sarviya, "Bio-fuels for the gas turbine: A review," Renewable and Sustainable Energy Reviews, vol. 14, no. 9, pp. 2946–2955, Dec. 2010. DOI: https://doi.org/10.1016/j.rser.2010.07.025
G. Liu, B. Yan, and G. Chen, "Technical review on jet fuel production," Renewable and Sustainable Energy Reviews, vol. 25, pp. 59–70, Sep. 2013. DOI: https://doi.org/10.1016/j.rser.2013.03.025
D. Chiaramonti, M. Prussi, M. Buffi, and D. Tacconi, "Sustainable bio kerosene: Process routes and industrial demonstration activities in aviation biofuels," Applied Energy, vol. 136, pp. 767–774, Dec. 2014. DOI: https://doi.org/10.1016/j.apenergy.2014.08.065
U. Neuling and M. Kaltschmitt, "Conversion routes for production of biokerosene—status and assessment," Biomass Conversion and Biorefinery, vol. 5, no. 4, pp. 367–385, Dec. 2015. DOI: https://doi.org/10.1007/s13399-014-0154-2
M. Mohammad, T. Kandaramath Hari, Z. Yaakob, Y. Chandra Sharma, and K. Sopian, "Overview on the production of paraffin based-biofuels via catalytic hydrodeoxygenation," Renewable and Sustainable Energy Reviews, vol. 22, pp. 121–132, Jun. 2013. DOI: https://doi.org/10.1016/j.rser.2013.01.026
W.-C. Wang and L. Tao, "Bio-jet fuel conversion technologies," Renewable and Sustainable Energy Reviews, vol. 53, pp. 801–822, Jan. 2016. DOI: https://doi.org/10.1016/j.rser.2015.09.016
J. Yang, Z. Xin, Q. (Sophia) He, K. Corscadden, and H. Niu, "An overview on performance characteristics of bio-jet fuels," Fuel, vol. 237, pp. 916–936, Feb. 2019. DOI: https://doi.org/10.1016/j.fuel.2018.10.079
T. Wang et al., "Aviation fuel synthesis by catalytic conversion of biomass hydrolysate in aqueous phase," Applied Energy, vol. 136, pp. 775–780, Dec. 2014. DOI: https://doi.org/10.1016/j.apenergy.2014.06.035
J. Fu, C. Yang, J. Wu, J. Zhuang, Z. Hou, and X. Lu, "Direct production of aviation fuels from microalgae lipids in water," Fuel, vol. 139, pp. 678–683, Jan. 2015. DOI: https://doi.org/10.1016/j.fuel.2014.09.025
Y. Zhang et al., "Production of jet and diesel biofuels from renewable lignocellulosic biomass," Applied Energy, vol. 150, pp. 128–137, Jul. 2015. DOI: https://doi.org/10.1016/j.apenergy.2015.04.023
Q. Liu, C. Zhang, N. Shi, X. Zhang, C. Wang, and L. Ma, "Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones," RSC Advances, vol. 8, no. 25, pp. 13686–13696, 2018. DOI: https://doi.org/10.1039/C8RA01723A
"The Plant List: A Working List of All Plant Species." http://www.theplantlist.org.
R. Upton, "Stinging nettles leaf (Urtica dioica L.): Extraordinary vegetable medicine," Journal of Herbal Medicine, vol. 3, no. 1, pp. 9–38, Mar. 2013. DOI: https://doi.org/10.1016/j.hermed.2012.11.001
Z. Jafari, S. A. Samani, and M. Jafari, "Insights into the bioactive compounds and physico-chemical characteristics of the extracted oils from Urtica dioica and Urtica pilulifera," SN Applied Sciences, vol. 2, no. 3, Feb. 2020, Art. no. 416. DOI: https://doi.org/10.1007/s42452-020-2219-0
S. Gurkan Aydin and A. Ozgen, "Sustainable Jet Fuel Production: Using Pumpkin Seed Oil," TEM Journal, vol. 10, no. 2, pp. 879–882, 2021. DOI: https://doi.org/10.18421/TEM102-49
S. G. Aydin, O. Polat, A. Ozgen, and E. Turali, "Calculated Optimized Structure and Geometric Analysis of Oxygenated Fuel Additives: Alcohols and Ethers," Engineering, Technology & Applied Science Research, vol. 10, no. 3, pp. 5632–5636, Jun. 2020. DOI: https://doi.org/10.48084/etasr.3491
A. A. Khaskheli, G. D. Walasai, A. S. Jamali, Q. B. Jamali, Z. A. Siyal, and A. Mengal, "Performance Evaluation of Locally-Produced Waste Cooking Oil Biodiesel with Conventional Diesel Fuel," Engineering, Technology & Applied Science Research, vol. 8, no. 6, pp. 3521–3524, Dec. 2018. DOI: https://doi.org/10.48084/etasr.2333
I. Naim and T. Mahara, "Fuel Substitution for Energy Saving: A Case Study of Foundry Plant," Engineering, Technology & Applied Science Research, vol. 8, no. 5, pp. 3439–3444, Oct. 2018. DOI: https://doi.org/10.48084/etasr.2298
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