Elaboration and Physico-Chemical Characterization of the Gibbsite Li(OH)3 Hybrid Material

Authors

  • N. el H. Belkham Department of Chemical Engineering, LMPMP Laboratory, Ferhat Abbas Sétif I University, Algeria
  • D. Benachour Department of Chemical Engineering, LMPMP Laboratory, Ferhat Abbas Sétif I University, Algeria
  • A. Mehamha Center of Mineral Technology and Plasturgy, Canada
Volume: 11 | Issue: 1 | Pages: 6740-6744 | February 2021 | https://doi.org/10.48084/etasr.3988

Abstract

A hybrid material can be defined as a combination of two components of different chemical nature. The combination of a mineral matrix and organic matter has multiple significance. From a chemical point of view, it allows the obtaining of bi-functional materials that combine the chemical properties of their components. The development of new materials with specific properties and nanostructured Lamellar Double Hydroxides (LDHs) has been widely investigated due to their great importance. This study focuses on the development of a hybrid material consisting of a matrix of alumina trihydrate Al(OH)3 (gibbsite). Previous studies on the synthesis of suspension LDHs by lithium salts intercalation in a gibbsite matrix were examined, while the obtained samples were characterized by different physicochemical methods.

Keywords:

alumina, inorganic compounds, gibbsite, lithium-salts intercalation, lamellar double hydroxide components

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References

L. Madani, K. S. Belkhir, and S. Belkhiat, "Experimental Study of Electric and Dielectric Behavior of PVC Composites," Engineering, Technology & Applied Science Research, vol. 10, no. 1, pp. 5233-5236, Feb. 2020. https://doi.org/10.48084/etasr.3246

B. Uzbas and A. C. Aydin, "Microstructural Analysis of Silica Fume Concrete with Scanning Electron Microscopy and X-Ray Diffraction," Engineering, Technology & Applied Science Research, vol. 10, no. 3, pp. 5845-5850, Jun. 2020. https://doi.org/10.48084/etasr.3288

N. Zaman, S. Ahmed, M. Sanaullah, A. U. Rehman, A. R. Shar, and M. R. Luhur, "Fabrication and Characterization of Organoclay Reinforced Polyester Based Hybrid Nanocomposite Materials," Engineering, Technology & Applied Science Research, vol. 8, no. 3, pp. 3038-3040, Jun. 2018. https://doi.org/10.48084/etasr.1977

T. A. Zamoshchina, A. S. Saratikov, V. P. Isupov, and L. E. Chupakhina, "Synthesis and psychotropic activity of new long-acting lithium compounds," Pharmaceutical Chemistry Journal, vol. 27, no. 3, pp. 185-187, Mar. 1993. https://doi.org/10.1007/BF00772994

R. Salomão, L. M. Milena, M. H. Wakamatsu, and V. C. Pandolfelli, "Hydrotalcite synthesis via co-precipitation reactions using MgO and Al(OH)3 precursors," Ceramics International, vol. 37, no. 8, pp. 3063-3070, Dec. 2011. https://doi.org/10.1016/j.ceramint.2011.05.034

L. Lei, F. Millange, R. I. Walton, and D. O'Hare, "Efficient separation of pyridinedicarboxylates by preferential anion exchange intercalation in [LiAl2(OH)6]Cl•H2O," Journal of Materials Chemistry, vol. 10, no. 8, pp. 1881-1886, Jan. 2000. https://doi.org/10.1039/b002719g

M. Nayak, T. R. N. Kutty, V. Jayaraman, and G. Periaswamy, "Preparation of the layered double hydroxide (LDH) LiAl 2 (OH) 7 •2H 2 O, by gel to crystallite conversion and a hydrothermal method, and its conversion to lithium aluminates," Journal of Materials Chemistry, vol. 7, no. 10, pp. 2131-2137, 1997. https://doi.org/10.1039/a702065a

N. F. Uvarov, B. B. Bokhonov, V. P. Isupov, and E. F. Hairetdinov, "Nanocomposite ionic conductors in the Li2SO4Al2O3 system," Solid State Ionics, vol. 74, no. 1, pp. 15-27, Dec. 1994. https://doi.org/10.1016/0167-2738(94)90432-4

R. Sihombing, Y. K. Krisnandi, R. Widya, S. Z. Luthfiyah, and R. T. Yunarti, "Adsorption of Phosphate Ion in Water with Lithium-Intercalated Gibbsite," Jurnal Internasional, vol. 19, no. 4, pp. 131-136, Mar. 2017. https://doi.org/10.7454/mss.v19i4.5166

K. A. Tarasov et al., "Formation of Nanosized Metal Particles of Cobalt, Nickel, and Copper in the Matrix of Layered Double Hydroxide," Journal of Materials Synthesis and Processing, vol. 8, no. 1, pp. 21-27, Jan. 2000.

L. Huang et al., "Synthesis of LiAl2-layered double hydroxides for CO2 capture over a wide temperature range," Journal of Materials Chemistry A, vol. 2, no. 43, pp. 18454-18462, Oct. 2014. https://doi.org/10.1039/C4TA04065A

V. P. Isupov, "Intercalation compounds of aluminum hydroxide," Journal of Structural Chemistry, vol. 40, no. 5, pp. 672-685, Sep. 1999. https://doi.org/10.1007/BF02903444

A. M. Fogg, J. S. Dunn, S.-G. Shyu, D. R. Cary, and D. O'Hare, "Selective Ion-Exchange Intercalation of Isomeric Dicarboxylate Anions into the Layered Double Hydroxide [LiAl2(OH)6]Cl•H2O," Chemistry of Materials, vol. 10, no. 1, pp. 351-355, Jan. 1998. https://doi.org/10.1021/cm9705202

A. P. Nemudry, V. P. Isupov, N. P. Kotsupalo, and V. V. Boldyrev, "Reaction of crystalline aluminium hydroxide with aqueous solutions of lithium salts," Reactivity of Solids, vol. 1, no. 3, pp. 221-226, May 1986. https://doi.org/10.1016/0168-7336(86)80002-X

S. G. Kozlova, S. P. Gabuda, V. P. Isupov, and L. É. Chupakhina, "Structural Effects of Intercalation in [LiAl2(OH)6]Cl ⋅ xH2Os (1H, 7Li, 27Al NMR)," Journal of Structural Chemistry, vol. 42, no. 2, pp. 189-192, Mar. 2001. https://doi.org/10.1023/A:1010490629431

K. R. Poeppelmeier and S. J. Hwu, "Synthesis of lithium dialuminate by salt imbibition," Inorganic Chemistry, vol. 26, no. 20, pp. 3297-3302, Oct. 1987. https://doi.org/10.1021/ic00267a017

A. M. Fogg and D. O'Hare, "Study of the Intercalation of Lithium Salt in Gibbsite Using Time-Resolved in Situ X-ray Diffraction," Chemistry of Materials, vol. 11, no. 7, pp. 1771-1775, Jul. 1999. https://doi.org/10.1021/cm981151s

J. Twu and P. K. Dutta, "Structure and reactivity of oxovanadate anions in layered lithium aluminate materials," The Journal of Physical Chemistry, vol. 93, no. 23, pp. 7863-7868, Nov. 1989. https://doi.org/10.1021/j100360a028

A. V. Besserguenev and al., "Synthesis and structure of the gibbsite intercalation compounds [LiAl2(OH)6]X (X ) Cl, Br, NO3) and [LiAl2(OH)6]XâH2Ousing synchrotron X-ray and neutron powder diffraction", Chemistry of Materials, Vol. 9, No. 1, pp. 241-247, 1997 . doi:10.1021/cm960316z. https://doi.org/10.1021/cm960316z

K. A. Tarasov, V. P. Isupov, L. E. Chupakhina, and D. O'Hare, "A time resolved, in-situ X-ray diffraction study of the de-intercalation of anions and lithium cations from [LiAl2(OH)6]nX•qH2O (X = Cl−, Br−, NO3−, SO42−)," Journal of Materials Chemistry, vol. 14, no. 9, pp. 1443-1447, Apr. 2004. https://doi.org/10.1039/B314473A

A. M. Fogg, A. J. Freij, and G. M. Parkinson, "Synthesis and Anion Exchange Chemistry of Rhombohedral Li/Al Layered Double Hydroxides," Chemistry of Materials, vol. 14, no. 1, pp. 232-234, Jan. 2002. https://doi.org/10.1021/cm0105099

J. L. Burba III, "Crystalline lithium aluminates," US4348295A, Sep. 07, 1982.

P. K. Dutta and M. Puri, "Anion exchange in lithium aluminate hydroxides," The Journal of Physical Chemistry, vol. 93, no. 1, pp. 376-381, Jan. 1989. https://doi.org/10.1021/j100338a072

S. W. Rhee, J. H. Lee, and D.-Y. Jung, "Quantitative Analyses of Shape-Selective Intercalation of Isomeric Mixtures of Muconates into [LiAl2(OH)6]Cl•yH2O Layered Double Hydroxide," Journal of Colloid and Interface Science, vol. 245, no. 2, pp. 349-355, Jan. 2002. https://doi.org/10.1006/jcis.2001.8034

B. R. Sundlof and W. M. Carty, "Organic and Inorganic Dispersion of Alumina," in Materials & Equipment/Whitewares: Ceramic Engineering and Science Proceedings, John Wiley & Sons, Ltd, 1999, pp. 151-166. https://doi.org/10.1002/9780470294543.ch15

D. W. Bruce and D. O'Hare, Inorganic Materials, 2nd ed. Chichester, UK: John Wiley & Sons, 1996.

A. J. Jacobson, "Intercalation Reactions of Layered Compounds," in Solid State Chemistry, vol. 2: Compounds, Oxford, New York: Oxford University Press, 1992, Art. no. 182.

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[1]
N. el H. . Belkham, D. Benachour, and A. Mehamha, “Elaboration and Physico-Chemical Characterization of the Gibbsite Li(OH)3 Hybrid Material”, Eng. Technol. Appl. Sci. Res., vol. 11, no. 1, pp. 6740–6744, Feb. 2021.

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