Growth Mode Study of MgCl2 on Ti (0001) and SiO2 under Ultra High Vacuum by XPS
Abstract
The growth mode of MgCl2 on Ti (0001) and on SiO2 grown on Si (100) was investigated by X-ray Photoelectron Spectroscopy (XPS) under UHV conditions. Magnesium chloride grows on both Ti (0001) single crystal and SiO2 following the Frank-van der Merve, (FM) growth mode.
Keywords:
growth mode, MgCl2, Ti(0001), SiO2, UHV, XPSDownloads
References
P. Sobota, S. Szafert, “Ionization of TiCl4 and MgCl2 during the formation of a high-activity α-olefin polymerization catalyst. Crystal structure of [cis-{C2H4(CO2Et)2}2Cl2Ti][SbCl6]2×CH2Cl2 and [Mg{C2H4(CO2Et)2)3][MgCl4]×2CH2Cl2”, Inorg. Chem., Vol. 35, pp. 1778-1781, 1996 DOI: https://doi.org/10.1021/ic9504093
E. Magni, G. A. Somorjai, “Preparation and Surface Science Characterization of Model Ziegler−Natta Catalysts. Role of Undercoordinated Surface Magnesium Atoms in the Chemisorption of TiCl4on MgCl2 Thin Films”, J. Phys. Chem. B., Vol. 102, No. 44, pp. 8788-8795, 1998 DOI: https://doi.org/10.1021/jp982017y
A. Andoni, J. C. Chadwick, S. Milani, H. J.W. Niemantsverdriet, P. C. Thüne, “Introducing a new surface science model for Ziegler–Natta catalysts: Preparation, basic characterization and testing”, Journal of Catalysis, Vol. 247, No. 2, pp. 129-136, 2007 DOI: https://doi.org/10.1016/j.jcat.2007.01.019
S. Karakalos, A. Siokou, V. Dracopoulos, F. Sutara, T. Skala, M. Skoda, S. Ladas, K. Prince, V. Matolin, V. Chab, “The interfacial properties of Mg Cl2 thin films grown on Si (111) 7×7”, Journal of Chemical Physics, Vol. 128, art. no. 104705, 2008 DOI: https://doi.org/10.1063/1.2888926
S. Karakalos, A. Siokou, S. Ladas, “The interfacial properties of MgCl2 films grown on a flat SiO2/Si substrate. An XPS and ISS study”, Applied Surface Science, Vol. 255, pp. 8941-8946, 2009 DOI: https://doi.org/10.1016/j.apsusc.2009.06.105
R.K. Iler, The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties and Biochemistry, Wiley-Interscience, Chichester, 1979
J. C. Chadwick, “Ziegler–Natta catalysts”, Encyclopedia Polym. Sci. Technol., Vol. 6, p. 517, 2003 DOI: https://doi.org/10.1016/S1351-4180(03)00031-X
P. Corradini, V. Busico, G. Guerra, Comprehensive Polymer Science, Vol. 4, Pergamon Press, p. 29, 1988 DOI: https://doi.org/10.1016/B978-0-08-096701-1.00118-X
S. Karakalos, A. Siokou, F. Sutara, T. Skala, F. Vitaliy, S. Ladas, K. Prince, V. Matolin, V. Chab, “The interfacial properties of MgCl2 thin films grown on Ti(0001)”, Journal of Chemical Physics, Vol. 133, art. no. 074701, 2010
Downloads
How to Cite
License
Authors who publish with this journal agree to the following terms:
- Authors retain the copyright and grant the journal the right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) after its publication in ETASR with an acknowledgement of its initial publication in this journal.
